Answer:
Only changes in temperature will influence the equilibrium constant 
. The system will shift in response to certain external shocks. At the new equilibrium 
will still be equal to , but the final concentrations will be different.
The question is asking for sources of the shocks that will influence the value of . For most reversible reactions:
- External changes in the relative concentration of the products and reactants.
For some reversible reactions that involve gases:
- Changes in pressure due to volume changes.
Catalysts do not influence the value of . See explanation.
Explanation:
.
Similar to the rate constant, the equilibrium constant depends only on:
the standard Gibbs energy change of the reaction, and
the absolute temperature (in degrees Kelvins.)
The reversible reaction is in a dynamic equilibrium when the rate of the forward reaction is equal to the rate of the backward reaction. Reactants are constantly converted to products; products are constantly converted back to reactants. However, at equilibrium 
the two processes balance each other. The concentration of each species will stay the same.
Factors that alter the rate of one reaction more than the other will disrupt the equilibrium. These factors shall change the rate of successful collisions and hence the reaction rate.
- Changes in concentration influence the number of particles per unit space.
- Changes in temperature influence both the rate of collision and the percentage of particles with sufficient energy of reaction.
For reactions that involve gases,
- Changing the volume of the container will change the concentration of gases and change the reaction rate.
However, there are cases where the number of gases particles on the reactant side and the product side are equal. Rates of the forward and backward reaction will change by the same extent. In such cases, there will not be a change in the final concentrations. Similarly, catalysts change the two rates by the same extent and will not change the final concentrations. Adding noble gases will also change the pressure. However, concentrations stay the same and the equilibrium position will not change.
Substitution Reactions are those reactions in which one nucleophile replaces another nucleophile present on a substrate. These reactions can take place via two different mechanism i.e SN¹ or SN². In SN¹ substitution reactions the leaving group leaves first forming a carbocation and nucleophile attacks carbocation in the second step. While in SN² reactions the addition of Nucleophile and leaving of leaving group take place simultaneously.
Example:
OH⁻ + CH₃-Br → CH₃-OH + Br⁻
In above reaction,
OH⁻ = Incoming Nucleophile
CH₃-Br = Substrate
CH₃-OH = Product
Br⁻ = Leaving group
Organic reactions are typically slower than ionic reactions because in organic compounds the covalent bonds are first broken, this breaking of bonds is a slower step, while, in ionic compounds no bond breakage is required as it consists of ions, so only bond formation takes place which is a quicker and fast step.
The double replacement reaction
<h3>Further explanation</h3>
Given
Reaction if Na₂S + HCl
Required
Type of reaction
Solution
The double replacement reaction occurs when there is a displacement of the cations and anions of the reactants involved in the reaction to form two new compounds.
The general formula for this reaction :
AB + CD ⇒ AD + CB
At the bottom of the reaction, it is shown the number of atoms of each compound in the reactants and products which indicates the application of <em>the law of conservation of mass</em>, that the number of atoms in the reactants will be the same as the number of atoms in the product, so the reaction is said to be in a balanced state.
