1) Calculate the number of moles of O2 (g) in 300 cm^3 of gas at 298 k and 1 atm
Ideal gas equation: pV = nRT => n = pV / RT
R = 0.0821 atm*liter/K*mol
V = 300 cm^3 = 0.300 liter
T = 298 K
p = 1 atm
=> n = 1 atm * 0.300 liter / [ (0.0821 atm*liter /K*mol) * 298K] = 0.01226 mol
2) The reaction of a metal with O2(g) to form an ionic compound (with O2- ions) is of the type
X (+) + O2 (g) ---> X2O or
2 X(2+) + O2(g) ----> X2O2 = 2XO or
4X(3+) + 3O2(g) ---> 2X2O3
In the first case, 1 mol of metal react with 1 mol of O2(g); in the second case, 2 moles of metal react with 1 mol of O2(g); in the third, 4 moles of X react with 3 moles of O2(g)
So, lets probe those 3 cases.
3) Case 1: 1 mol of metal X / 1 mol O2(g) = x moles / 0.01226 mol
=> x = 0.01226 moles of metal X
Now you can calculate the atomic mass of the hypotethical metal:
1.15 grams / 0.01226 mol = 93.8 g / mol
That does not correspond to any of the metal with valence 1+
So, now probe the case 2.
4) Case 2:
2moles X metal / 1 mol O2(g) = x / 0.01226 mol
=> x = 2 * 0.01226 = 0.02452 mol
And the atomic mass of the metal is: 1.15 g / 0.02452 mol = 46.9 g/mol
That is similar to the atomic mass of titanium which is 47.9 g / mol and whose valece is 2+.
4) Case 3
4 mol meta X / 3 mol O2 = x / 0.01226 => x = 0.01226 * 4 / 3 = 0.01635
atomic mass = 1.15 g / 0.01635 mol = 70.33 g/mol
That does not correspond to any metal.
Conclusion: the identity of the metallic element could be titanium.
Answer:
Please find the complete solution in the attached file.
Explanation:
Answer:
1.62 L
Explanation:
T= 97+273.15= 370.15
R= 0.08206 atm/mol⋅K
V= 45 L
n= 2.4 mol
P= (n⋅R⋅T)/V
= (2.4 x 0.08206 x 370.15)/(45) = 1.61997 = 1.62
Answer:
a) galvanic cell
b)electrolytic cell
c) i) K=6.27x10'34
ΔG°=198790 J
ii) K=3.58x10'-34
ΔG°= 191070 J
d) E°=0.278 v
ΔG°= -26827 J
Explanation:
a) There are two kinds of an electrochemical cell, the first is called "galvanic cells", and the second "electrolytic cell".
The fuel cells are capable of produce electric energy through chemical reactions. These reactions are often spontaneous. So, the galvanic cell has a negative value for Gibbs free energy.
b) The electrolytic cell increases the value of Gibbs energy, to positive values, due to the reactions are not spontaneous.
c) i) look image attached
ii) k = look image attached
ΔG° = -nFE° = - 6 X 95500 J/vmole x (-0.33 v)
ΔG° =-191070
d) E°= 0.0592 v/n x lg K
E°= 0.0592V / 1 X log 5.0X10'4
E°= 0.278 v
ΔG° = -nFE° = -1 x 96500 J/ vmole x 0.278v
ΔG° = -26827 J
Answer:
<u><em>When balloon filled with the helium gas is left in the car at night along with the decrease in temperature the size of the balloon will get smaller or it will look like little deflated</em></u>.The above observation can be explained on the basis of Charles law:The law states that 'under constant pressure ,the volume occupied by the gas is directly proportional to the temperature of the gas'. (At constant pressure)Temperature desecrate volume will also decreases and vice versa.So, with decrease in temperature at night the temperature of the gas in the balloon will also get decreased due to which the volume of the balloon will also get decreased.
Explanation:
