Answer:
Explanation:
The change is as follows
P₁ V₁ to 3P₁, V₁ ( constt volume ) --- first process
3P₁,V₁ to 3P₁ , 5V₁ ( constt pressure ) ---- second process
In the first process Temperature must have been increased 3 times . So if initial temperature is T₁ then final temperature will be 3 T₁
P₁V₁ = n R T₁ , n is no of moles of gas enclosed.
nRT₁ = P₁V₁
Heat added at constant volume = n Cv ( 3T₁ - T₁)
= n x 5/3 R X 2T₁ ( for diatomic gas Cv = 5/3 R)
= 10/3 x nRT₁
= 10/3x P₁V₁
In the second process, Temperature must have been increased 5 times . So if initial temperature is 3T₁ then final temperature will be 15 T₁
Heat added at constant pressure in second case
= n Cp ( 15T₁ - 3T₁)
= n x 7/3 R X 12T₁ ( For diatomic gas Cp = 7/3 R)
= 28 x nRT₁
= 28 P₁V₁
Answer:
The mass percentage of calcium nitrate is 31.23%.
Explanation:
Let the the mass of calcium nitrate be x and mass of potassium chloride be y.
Total mass of mixture = 19.12 g
x + y = 19.12 g..(1)
Mass of solvent = 149 g = 0.149 kg
Freezing point of the solution,
= -5.77 °C
Molal freezing constant of water = 1.86 °C/m =1.86 °C/(mol/kg)
The van't Hoff factor contribution by calcium nitrate is 3 and by potassium chloride is 2.So:
i = 3
i' = 2
Freezing point of water = T = 0°C
On solving we get:
....(2)
Solving equation (1)(2) for x and y:
x =5.973 g
y = 13.147 g
Mass percent of 
in the mixture:
The mass percentage of calcium nitrate is 31.23%.
The answer is D since work done must have displacement..if theres force but no displacement there will be no work done based on W=Fs
