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zhenek [66]
2 years ago
8

How to figure out which melting point would have the lowest melting point ?

Chemistry
2 answers:
77julia77 [94]2 years ago
8 0

Answer:

By evaluating the intermolecular forces and size!

Explanation:

Essentially the stronger the forces the higher the melting point... Here is a list of interemolecular forces (the first will be the weakest).

1) Dispersion forces (Exhibited by evrey molecule) (Weakest)

2) Dipole-Dipole

3) Hydrogen bonding

4) Ionic bonds (Strongest)

The stronger the forces it has then the higher the melting point. Also aromatic structures have a higher melting point as well. A general rule of thumb is, the larger the structure is then the higher thee melting point it.

stellarik [79]2 years ago
6 0

Answer:

That would be helium, with a melting point of 0.95 K (-272.20 °C)—although this happens only under considerable pressure (~25 atmospheres). At ordinary pressure, helium would remain liquid even if it could be chilled to absolute zero.

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Calculate the pH of each of the following solutions: (a) 0.1000M Propanoic acid (HC3H5O2, Ka= 1.3x10-5 ) (b) 0.1000M sodium prop
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(a) The pH of 0.1000 M propanoic acid (HC3H5O2) is 2.9.

(b) The pH of 0.1000 M sodium propanoate (NaC3H5O2) is 8.9.

(c) The pH of 0.1000 M propanoic acid (HC3H5O2) and 0.1000 M sodium propanoate (NaC3H5O2) is 4.9.

<h3>Further explanation:</h3>

(a)

Given information:

The value of acid ionization constant for propanoic acid is  1.3 x 10^{-5} .

The initial concentration of propanoic acid is  .

To calculate:

The pH of 0.1000 M propanoic acid solution.

Solution:

Propanoic acid  is a weak acid. It ionizes partially in water as follows:

 

The expression for acid dissociation constant is,

                                                            …… (1)

Here,

 is ionization constant of propanoic acid.

is the equilibrium concentration of propanoate ion.

is the equilibrium concentration of hydronium ion.

 is the equilibrium concentration of propanoic acid.

ICE table (1):

 

Refer ICE table (1),

 

Substitute the values form the ICE table (1) in equation (1).

 

The approximation x is very small is valid. Therefore, the value of x can be neglected. Above equation can be modified as,

 

Rearrange above equation for x.

                                                                                                           …… (2)

Substitute   for   in equation (2) to calculate the value of x.

 

Therefore, from the ICE table (1) the concentration of hydronium ion is,

 .

The negative logarithm of hydronium ion concentration is defined as the pH of the solution. Mathematically,

                                                                                                               …… (3)

Substitute    for    in equation (3) to calculate the pH of the solution.

 

(b)

Given information:

The value of acid ionization constant for propanoic acid is  .

The initial concentration of sodium propanoate is  .

To calculate:

The pH of 0.1000 M sodium propanoate solution.

Solution:

Sodium propanoate  is conjugate base of weak propanoic acid. It undergoes hydrolysis in water to yield hydroxide ion in the solution as follows:

                                                        …… (4)

Propanoic acid  is a weak acid. It ionizes partially in water as follows:

                                                       …… (5)

Dissociation reaction for water is written as follows:

                                                                                       …… (6)

From equation (4), (5), and (6) the relationship between   and   is,

                                                                                                                              …… (7)

Substitute   for   and   for   in equation (7).

 

ICE table (2):

 

The expression for base dissociation constant is,

                                                                                                     …… (8)

Here,

is base ionization constant.

is the equilibrium concentration of propanoate ion.

is the equilibrium concentration of hydroxide ion.

 is the equilibrium concentration of propanoic acid.

From the ICE table (2),

 

Substitute the values form the ICE table (2) in equation (8).

 

The approximation y is very small is valid. Therefore, the value of y can be neglected. Above equation can be modified as,

 

Rearrange above equation for y.

                                                                                                           …… (9)

Substitute   for   in equation (9) to calculate the value of y.

 

Therefore, from the ICE table (2) the concentration of hydroxide ion is,

 

The negative logarithm of hydroxide ion concentration is defined as pOH of the solution. Mathematically,

                                                                                                           …… (10)

Substitute    for    in equation (10) to calculate pOH of the solution.

 

The relation between pH and pOH is as follows:

                                                                                                                   …… (11)

Substitute 5.057 for pOH in equation (11) to calculate the pH of the solution.

 

(c)

Given information:

The value of acid ionization constant for propanoic acid is  .

The initial concentration of sodium propanoate is  .

The initial concentration of sodium propanoate is  .

To calculate:

The pH of 0.1000 M sodium propanoate and 0.1000 M propanoic acid solution.

Solution:

Propanoic acid is a weak acid, and sodium propanoate is salt of the conjugate base of propanoic acid. Thus, propanoic acid and sodium propanoate will form a buffer system.

The pH of the buffer solution can be determined with the help of the Henderson-Hasselbalch equation. Mathematically,

 

For propanoic acid and sodium propanoate buffer system, the Henderson-Hasselbalch equation can be modified as,

                                                                                               …… (12)

The negative logarithm of acid ionization constant is equal to  .

                                                                                                                …… (13)

Substitute   for  in equation (13).

 

Substitute    for  ,   for   and 4.9 for    in equation (12).

 

Learn more:

1. About Henderson-Hasselbalch equation brainly.com/question/12999557

2. Learn more about how to calculate moles of the base in given volume brainly.com/question/4283309

Answer details:

Grade: Senior School

Subject: Chemistry

Chapter: Ionic equilibria

Keywords: ionic equilibrium, propanoic acid, sodium propanoate, ionization constant, weak acid, conjugate base, equilibrium concentration, hydronium ion, hydroxide ion, pH, pOH, ICE table, negative logarithm, buffer solution, Henderson-Hasselbalch equation, 0.1000 M, 4.9, 8.9, 2.9.

3 0
3 years ago
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Write a net ionic equation for the overall reaction that occurs when aqueous solutions of hydrosulfuric acid (H2S) and sodium hy
erica [24]

Answer:

H2S(g) + 2OH^-(aq) -------->  S^2-(aq) + 2H2O(l)

Explanation:

We know that the net ionic equation shows the major reaction that occurs in the reaction system.

The molecular reaction equation is;

H2S(g) + 2NaOH(aq) ------> Na2S(aq) + 2H2O(l)

The complete ionic equation is;

H2S(g) + 2Na^+(aq) + 2OH^-(aq) --------> 2Na^+(aq) + S^2-(aq) + 2H2O(l)

Net ionic equation;

H2S(g) + 2OH^-(aq) -------->  S^2-(aq) + 2H2O(l)

3 0
2 years ago
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