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The original concentration of the acid solution is 6.175 10^-4 mol / L.
<u>Explanation:</u>
Concentration is the ratio of solute in a solution to either solvent or total solution. It is expressed in terms of mass per unit volume
HBr + NaOH -----> NaBr + H2O
There is a 1:1 equivalence with acid and base.
Moles of NaOH = 72.90 10^-3
0.25
= 0.0182 mol.
[ HBr ] = moles of base / volume of a solution
= 0.0182 / 29.47
= 6.175 10^-4 mol / L.