Missing in your question Ka2 =6.3x10^-8
From this reaction:
H2SO3 + H2O ↔ H3O+ + HSO3-
by using the ICE table :
H2SO3 ↔ H3O + HSO3-
intial 0.6 0 0
change -X +X +X
Equ (0.6-X) X X
when Ka1 = [H3O+][HSO3-]/[H2SO3]
So by substitution:
1.5X10^-2 = (X*X) / (0.6-X) by solving this equation for X
∴ X = 0.088
∴[H2SO3] = 0.6 - 0.088 = 0.512
[HSO3-] = [H3O+] = 0.088
by using the ICE table 2:
HSO3- ↔ H3O + SO3-
initial 0.088 0.088 0
change -X +X +X
Equ (0.088-X) (0.088+X) X
Ka2= [H3O+] [SO3-] / [HSO3-]
we can assume [HSO3-] = 0.088 as the value of Ka2 is very small
6.3x10^-8 = (0.088+X)*X / 0.088
X^2 +0.088 X - 5.5x10^-9= 0 by solving this equation for X
∴X= 6.3x10^-8
∴[H3O+] = 0.088 + 6.3x10^-8
= 0.088 m ( because X is so small)
∴PH= -㏒[H3O+]
= -㏒ 0.088 = 1.06
Answer:
-800 kJ/mol
Explanation:
To solve the problem, we have to express the enthalpy of combustion (ΔHc) in kJ per mole (kJ/mol).
First, we have to calculate the moles of methane (CH₄) there are in 2.50 g of substance. For this, we divide the mass into the molecular weight Mw) of CH₄:
Mw(CH₄) = 12 g/mol C + (1 g/mol H x 4) = 16 g/mol
moles CH₄ = mass CH₄/Mw(CH₄)= 2.50 g/(16 g/mol) = 0.15625 mol CH₄
Now, we divide the heat released into the moles of CH₄ to obtain the enthalpy per mole of CH₄:
ΔHc = heat/mol CH₄ = 125 kJ/(0.15625 mol) = 800 kJ/mol
Therefore, the enthalpy of combustion of methane is -800 kJ/mol (the minus sign indicated that the heat is released).
It would be 35.8 Calories or calories. Not sure about that part. Hope this helps though.
5.2 km to mm.
1km = 1000m
= 5.2 * 1000m.
=5200 m. 1m = 1000mm
= 5200 * 1000mm
= 5200000 mm
