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A buffer solution is made that is 0.347 M in H2C2O4 and 0.347 M KHC2O4.

irga5000 [103]

Answer:

1. pH = 1.23.

2. $H_2C_2O_4(aq) +OH^-(aq)\rightarrow HC_2O_4^-(aq)+H_2O(l)$

Explanation:

Hello!

1. In this case, for the ionization of H2C2O4, we can write:

$H_2C_2O_4\rightleftharpoons HC_2O_4^-+H^+$

It means, that if it is forming a buffer solution with its conjugate base in the form of KHC2O4, we can compute the pH based on the Henderson-Hasselbach equation:

$pH=pKa+log(\frac{[base]}{[acid]} )$

Whereas the pKa is:

$pKa=-log(Ka)=-log(5.90x10^{-2})=1.23$

The concentration of the base is 0.347 M and the concentration of the acid is 0.347 M as well, as seen on the statement; thus, the pH is:

$pH=1.23+log(\frac{0.347M}{0.347M} )\\\\pH=1.23+0\\\\pH=1.23$

2. Now, since the addition of KOH directly consumes 0.070 moles of acid, we can compute the remaining moles as follows:

$n_{acid}=0.347mol/L*1.00L=0.347mol\\\\n_{acid}^{remaining}=0.347mol-0.070mol=0.277mol$

It means that the acid remains in excess yet more base is yielded due to the effect of the OH ions provided by the KOH; therefore, the undergone chemical reaction is:

$H_2C_2O_4(aq) +OH^-(aq)\rightarrow HC_2O_4^-(aq)+H_2O(l)$

Which is also shown in net ionic notation.

Best regards!

4 0

3 years ago

g 2BrO3- + 5SnO22-+ H2O5SnO32- + Br2+ 2OH- In the above reaction, the oxidation state of tin changes from to . How many electron

Archy [21]

Answer:

In the above reaction, the oxidation state of tin changes from 2+ to 4+.

10 moles of electrons are transferred in the reaction

Explanation:

Redox reaction is:

2BrO₃⁻ + 5SnO₂²⁻ + H2O ⇄ 5SnO₃²⁻ + Br₂ + 2OH⁻

SnO₂²⁻ → SnO₃²⁻

Tin changes the oxidation state from +2 to +4. It has increased it so this is the oxidation from the redox (it released 2 e⁻). We are in basic medium, so we add water in the side of the reaction where we have the highest amount of oxygen. We have 2 O on left side and 3 O on right side so we add 1 water on the right and we complete with OH⁻ in the opposite side to balance the H.

SnO₂²⁻ + 2OH⁻ → SnO₃²⁻ + 2e⁻ + H₂O <u>Oxidation</u>

BrO₃⁻ → Br₂

First of all, we have unbalance the bromine, so we add 2 on the BrO₃⁻. We have 6 O in left side and there are no O on the right, so we add 6 H₂O on the left. To balance the H, we must complete with 12OH⁻. Bromate reduces to bromine at ground state, so it gained 5e⁻. We have 2 atoms of Br, so finally it gaines 10 e⁻.

6H₂O + 10 e⁻ + 2BrO₃⁻ → Br₂ + 12OH⁻ <u>Reduction</u>

In order to balance the main reaction and balance the electrons we multiply (x5) the oxidation and (x1) the reduciton

(SnO₂²⁻ + 2OH⁻ → SnO₃²⁻ + 2e⁻ + H₂O) . 5

(6H₂O + 10 e⁻ + 2BrO₃⁻ → Br₂ + 12OH⁻) . 1

5SnO₂²⁻ + 10OH⁻ + 6H₂O + 10 e⁻ + 2BrO₃⁻ → Br₂ + 12OH⁻ + 5SnO₃²⁻ + 10e⁻ + 5H₂O

We can cancel the e⁻ and we substract:

12OH⁻ - 10OH⁻ = 2OH⁻ (on the right side)

6H₂O - 5H₂O = H₂O (on the left side)

2BrO₃⁻ + 5SnO₂²⁻ + H2O ⇄ 5SnO₃²⁻ + Br₂ + 2OH⁻

6 0

4 years ago

What scientific instrument is capable of measuring very small masses?

marusya05 [52]

Answer:

Electronic balances.

Explanation:

5 0

3 years ago

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Before raw data can be used as scientific evidence, it must be analyzed and summarized. One way of summarizing data is to find t

Nikitich [7]

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3 years ago