Direct electron transfer from a a singlet reduced species to a triplet oxidizing species is quantum-mechanically forbidden.
<h3><u>Transfer from singlet to triplet:</u></h3>
- Either an excited singlet state or an excited triplet state will occur when an electron in a molecule with a singlet ground state is stimulated (through radiation absorption) to a higher energy level.
- All electron spins in a molecule electronic state known as a singlet are coupled.
- In other words, the ground state electron and the stimulated electron's spin are still coupled (a pair of electrons in the same energy level must have opposite spins, per the Pauli exclusion principle).
- The excited electron and ground state electron are parallel in a triplet state because they are no longer coupled (same spin).
- It is less likely that a triplet state would arise when the molecule absorbs radiation since excitation to a triplet state necessitates an additional "forbidden" spin transfer.
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A chemical substance has the characteristics that it cannot be separated by physical methods. Seawater and milk can be separated by sedimentation, and air has different components depending on other aspects (such as elevation). Only ammonia is a substance. (thus it can have a formula: NH<span>3)</span>
Answer:
72.6 grams
Explanation:
I got this answer through stoichiometry. For every 1 mole of Mg, 2 moles of CuBr are consumed. Because of this, multiply the moles of Mg by 2. Then, convert moles to grams.
Answer:
IV
Explanation:
The complete question is shown in the image attached.
Let us call to mind the fact that the SN1 mechanism involves the formation of carbocation in the rate determining step. The order of stability of cabocations is; tertiary > secondary > primary > methyl.
Hence, a tertiary alkyl halide is more likely to undergo nucleophilic substitution reaction by SN1 mechanism since it forms a more stable cabocation in the rate determining step.
Structure IV is a tertiary alkyl halide, hence it is more likely to undergo nucleophilic substitution reaction by SN1 mechanism.
Answer:
Explanation:
The pressure is constant, so we can use Charles' Law to calculate the volume.
Data:
V₁ = 22.4 L; T₁ = 273.15 K
V₂ = ?; T₂ = 136.58 K
Calculations:
