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zlopas [31]
2 years ago
15

15.24. Calcium hydroxide, also known as slaked lime, is used in industrial processes in which low concentrations of base are req

uired. Only 0.16 g of Ca(OH)2 dissolves in 100 mL of water at 25°C. What is the concentration of hydroxide ions in 250 mL of a solution containing the maximum amount of dissolved calcium hydroxide?​
Chemistry
1 answer:
Ivahew [28]2 years ago
7 0

The concentration of the hydroxide ions, OH¯ in 250 mL of the solution containing the maximum amount of dissolved calcium hydroxide is 0.01728 M

We'll begin by calculating the number of mole of in 0.16 g of Ca(OH)₂. This can be obtained as follow:

Mass of Ca(OH)₂ = 0.16 g

Molar mass of Ca(OH)₂ = 40 + 2[16 + 1] = 74 g/mol

<h3>Mole of Ca(OH)₂ =? </h3>

Mole = mass / molar mass

Mole of Ca(OH)₂ = 0.16 / 74

<h3>Mole of Ca(OH)₂ = 0.00216 mole </h3>

  • Next, we shall determine the molarity of the stock solution of Ca(OH)₂.

Mole of Ca(OH)₂ = 0.00216 mole

Volume = 100 mL = 100 / 1000 = 0.1 L

<h3>Molarity of Ca(OH)₂ =? </h3>

Molarity = mole / Volume

Molarity of Ca(OH)₂ = 0.00216 / 0.1

<h3>Molarity of Ca(OH)₂ = 0.0216 M</h3>

  • Next, we shall determine the molarity of the diluted solution. This can be obtained as follow:

Volume of stock solution (V₁) = 100 mL

Molarity of stock solution (M₁) = 0.0216 M

Volume of diluted solution (V₂) = 250 mL

<h3>Molarity of diluted solution (M₂) =?</h3>

<h3>M₁V₁ = M₂V₂</h3>

0.0216 × 100 = M₂ × 250

2.16 = M₂ × 250

Divide both side by 250

M₂ = 2.16 / 250

<h3>M₂ = 0.00864 M</h3>

Thus, the molarity of the diluted solution is 0.00864 M

  • Finally, we shall determine the concentration of the hydroxide ions, OH¯ in the diluted solution. This can be obtained as follow:

Ca(OH)₂(aq) —> Ca²⁺(aq) + 2OH¯(aq)

From the balanced equation above,

1 mole of Ca(OH)₂ contains 2 moles of OH¯

Therefore,

0.00864 M Ca(OH)₂ will contain =  2 × 0.00864 = 0.01728 M OH¯

Thus, the concentration of the hydroxide ions, OH¯ in 250 mL of the solution containing the maximum amount of dissolved calcium hydroxide is 0.01728 M

Learn more: brainly.com/question/11471182

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What is the molarity of a 0.65L solution containing 63 grams of ? The molar mass of NaCl is 58.44 g/mol
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Explanation:

The molarity of a solution is defined like the number of moles of solute per liters of solution.

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If PbI2(s) is dissolved in 1.0MNaI(aq) , is the maximum possible concentration of Pb2+(aq) in the solution greater than, less th
fredd [130]

Answer:

\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}

Less than the concentration of Pb2+(aq) in the solution in part ( a )

Explanation:

From the question:

A)

We assume that s to be  the solubility of PbI₂.

The equation of the reaction is given as :

PbI₂(s) ⇌ Pb²⁺(aq) + 2I⁻(aq); Ksp = 7 × 10⁻⁹

 [Pb²⁺] =   s

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K_{sp} =\text{[Pb$^{2+}$][I$^{-}$]}^{2} = s\times (2s)^{2} =  4s^{3}\\s^{3} = \dfrac{K_{sp}}{4}\\\\s =\mathbf{ \sqrt [3]{\dfrac{K_{sp}}{4}}}\\\\\text{The mathematical expressionthat can be used to determine the value of  }\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}

B)

The Concentration of Pb²⁺  in water is calculated as :

\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}

\mathbf{s =\sqrt [3]{\dfrac{7*10^{-9}}{4}}}

\mathbf{s} =\sqrt[3]{1.75*10^{-9}}

\mathbf{s} =\mathbf{1.21*10^{-3}  \ mol/L }

The Concentration of Pb²⁺  in 1.0 mol·L⁻¹ NaI

\mathbf{PbCl{_2}}  \leftrightharpoons    \ \ \ \ \ \ \  \mathbf{Pb^{2+}}   \ \ \ \  \ +   \ \  \ \ \ \ \ \mathbf{2 I^-}

                             \ \ \ \ \ \ \  \ \   \ \  \ \ \ \ \ \ \  \mathbf0}   \ \ \ \  \ \ \ \ \ \   \ \ \ \ \ \mathbf{1.0}

                            \ \ \ \ \ \ \ \ \ \ \ \ \ \    \ \ \ \ \  \mathbf{+x}   \ \ \ \  \    \ \  \ \ \ \ \ \mathbf{+2x}

                            \ \ \ \ \ \ \ \ \ \ \ \ \ \    \ \ \ \ \  \mathbf{+x}   \ \ \ \  \    \ \  \ \ \ \ \ \mathbf{1.0+2x}

The equilibrium constant:

K_{sp} =[Pb^{2+}}][I^-]^2 \\ \\ K_{sp} = s*(1.0*2s)^2 =7*1.0^{-9} \\ \\ s = 7*10^{-9} \ \  m/L

It is now clear that maximum possible concentration of Pb²⁺ in the solution is less than that in the solution in part (A). This happens due to the  common ion effect. The added iodide ion forces the position of equilibrium to shift to the left, reducing the concentration of Pb²⁺.

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