Due to electronegativity difference between H and F atom.
<h3>
What is the reason for the difference ?</h3>
- The bond length of HF is 92 pm. It is 16% shorter than the sum of the covalent radii of H (37 pm) and F (72 pm).
- The shorter of the bond length is due to the difference in electronegativity between H and F atom. The electronegativity of F is 4.0, whereas the electronegativity of H is 2.1.
- Greater the difference of electronegativity between the bonded atoms, shorter will be the bond length.
- As becomes smaller i.e. as we proceed from HF to HI, this effect becomes lessens and bond length will be more predictable.
Thus from the above conclusion we can say the difference in electronegativity between H and F atom this is the reason for shorter bond length of HF.
Learn more about bond length here :
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<span>pre-1982 definition STP: 120 g/mol
post-1982 definition STP: 122 g/mol
The answer to this question depends upon which definition of STP you're using. The definition changed in 1982 from 273.15 K at 1 atmosphere to 273.15 K at 10000 pascals. As a result the molar volume of a gas at STP changed from 22.4 L/mol to 22.7 L/mol. So let's calculate the answer using both definitions and see if your text book is 35 years obsolete.
First, determine the number of moles of gas you have. Do this by dividing the volume you have by the molar volume. So
pre-1982: 0.04665 / 22.4 = 0.002082589 mol
post-1982: 0.04665 / 22.7 = 0.002055066 mol
Now divide the mass you have by the number of moles.
pre-1982: 0.250 g / 0.002082589 mol = 120.0428725 g/mol
post-1982: 0.250 g / 0.002055066 mol = 121.6505895 g/mol
Finally, round to 3 significant figures:
pre-1982: 120 g/mol
post-1982: 122 g/mol
These figures are insanely large for nitrogen gas. So let's see if our input data is reasonable. Looking up the density of nitrogen gas at STP, I get a value of 1.251 grams per liter. The value of 0.250 grams in the problem would then imply a volume of about one fifth of a liter, or about 200 mL. That is over 4 times the volume given of 46.65 mL. So the verbiage in the question mentioning "nitrogen gas" is inaccurate at best.
I see several possibilities.
1. The word "nitrogen" was pulled out of thin air and should be replaced with "an unknown"
2. The measurements given are incorrect and should be corrected.
In any case, if #1 above is the correct reason, then you need to pick the answer based upon which definition of STP your textbook is using.</span>
Hey there !
Mole ratio :
<span>2 KMnO4 + 16 HCl → 2 KCl + 2 MnCl2 + 8 H2O + 5 Cl2
2 moles KMnO4 ----------------- 8 moles H2O
3.45 moles KMnO4 ------------- (moles H2O )
Moles H2O = 3.45 * 8 / 2
Moles H2O = 27.6 / 2
= 13.8 moles of H2O
</span>The option that was given is wrong , <span>You're right.</span>
CS₂ + Cl₂<span> </span>→ CCl₄ + S₂Cl₂<span> [unbalanced equation]
</span>CS₂ + 3Cl₂ → CCl₄ + S₂Cl₂ [balanced equation]
∴ the mole ratio of Cl₂ : CCl₄ is 3 : 1 (option D)
1 or 8 i believe would be the answer
