Explanation:
The given reaction equation will be as follows.
![[FeSCN^{2+}] \rightleftharpoons [Fe^{3+}] + [SCN^{-}]](https://tex.z-dn.net/?f=%5BFeSCN%5E%7B2%2B%7D%5D%20%5Crightleftharpoons%20%5BFe%5E%7B3%2B%7D%5D%20%2B%20%5BSCN%5E%7B-%7D%5D)
Let is assume that at equilibrium the concentrations of given species are as follows.
M
M
M
Now, first calculate the value of
as follows.
![K_{eq} = \frac{[Fe^{3+}][SCN^{-}]}{[FeSCN^{2+}]}](https://tex.z-dn.net/?f=K_%7Beq%7D%20%3D%20%5Cfrac%7B%5BFe%5E%7B3%2B%7D%5D%5BSCN%5E%7B-%7D%5D%7D%7B%5BFeSCN%5E%7B2%2B%7D%5D%7D)
= 
= 
Now, according to the concentration values at the re-established equilibrium the value for
will be calculated as follows.
![K_{eq} = \frac{[Fe^{3+}][SCN^{-}]}{[FeSCN^{2+}]}](https://tex.z-dn.net/?f=K_%7Beq%7D%20%3D%20%5Cfrac%7B%5BFe%5E%7B3%2B%7D%5D%5BSCN%5E%7B-%7D%5D%7D%7B%5BFeSCN%5E%7B2%2B%7D%5D%7D)
M
Thus, we can conclude that the concentration of
in the new equilibrium mixture is
M.
Answer:
Because the value of K is huge.
Explanation:
The tautomer is a kind of isomer in which exist an equilibrium between a ketone and an enol, or between an aldehyde and an enol. So, in the enolization, the ketone is the reactant and the enol is the product.
The equilibrium reaction can be characterized by an equilibrium constant, which is the ratio of the concentration of the products by the concentration of the reactants.
Because the constant K is extremely large (10¹³) we can conclude that the concentration of the product will be greater than the concentration of the reactant, in the equilibrium. It means that the concentration of the enol will be greater.
So, the ketone is unstable and forms in a great amount the more stable product, the enol.
Answer:
your answer will be b) bonds are breaking
To get the answer you use the Law of Raoult.
Raoult's law states that the decrease of the vapor pressure of a liquid is proportional to the molar fraction of the solute.
ΔP = Pa * Xa
Here Pa = 0.038 atm
And Xa = N a / (Na + Nb), where Na is number of moles of A and Nb is number of moles of b
Na = mass of urea / molar mass of urea = 60 g / (molar mass of CH4N2O)
molar mass of CH4N2O = 12 g/mol + 4*1g/mol + 2*14 g/mol + 16 g/mol = 60 g/mol
Na = 60 g / 60 g/mol = 1 mol
Nb = mass of water / molar mass of water = 180g / 18g/mol = 10 mol
Xa = 1 mol / (10 mol + 1 mol) = 1/11 =0.09091
ΔP = Pb * Xa = 0.038 atm * 0.09091 = 0.0035 atm
Then, the final vapor pressure of water is Pb - ΔP = 0.038atm - 0.0035atm = 0.035 atm.
Answer: 0.035 atm