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Answer:
The standard enthalpy of formation of NOCl(g) at 25 ºC is 105 kJ/mol
Explanation:
The ∆H (heat of reaction) of the combustion reaction is the heat that accompanies the entire reaction. For its calculation you must make the total sum of all the heats of the products and of the reagents affected by their stoichiometric coefficient (number of molecules of each compound that participates in the reaction) and finally subtract them:
Enthalpy of the reaction= ΔH = ∑Hproducts - ∑Hreactants
In this case, you have: 2 NOCl(g) → 2 NO(g) + Cl₂(g)
So, ΔH=
Knowing:
- ΔH= 75.5 kJ/mol
= 90.25 kJ/mol
= 0 (For the formation of one mole of a pure element the heat of formation is 0, in this caseyou have as a pure compound the chlorine Cl₂)
=?
Replacing:
75.5 kJ/mol=2* 90.25 kJ/mol + 0 - 
Solving
-
=75.5 kJ/mol - 2*90.25 kJ/mol
-
=-105 kJ/mol
=105 kJ/mol
<u><em>The standard enthalpy of formation of NOCl(g) at 25 ºC is 105 kJ/mol</em></u>
Answer:
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Explanation:
Balance the equation first:
2 Fe+6 HNO3→2 Fe(NO3)3+3H2
Then calculate mass of Iron :
4.5×3.0×3.5 cm3(1 mL1 cm3)(7.87 g Fe1 ml)=371.86 g Fe
Now use Stoichiometry:
371.86 g Fe×(1 mol Fe55.85 g Fe)×(6 mol HNO32 mol Fe)=19.97 mol HNO3
Convert moles of nitric acid to grams
19.97 mol HNO3×(63.01 g HNO31 mol HNO3)=1258.3 g HNO3