First, we need to calculate the principal quantum number n for this electron, using the equation:
E = (-13.60 eV) / (n x n)
where E is the energy that is used to bound the electron (here, E = - 0.544 eV).
- 0.544 eV = (-13.60 eV) / (n x n)
n x n = (- 13.60 eV) / (- 0.544 eV)
n x n = 25
n = 5
The orbital radius that is equal to the radius of a hydrogen atom is calculated using the equation:
r = 0.053 nm x n x n
r = 0.053 nm x 5 x 5
r = 0.053 nm x 25
r = 1.325 nm
The answer is D. I did that and i got it right.
The molar mass for PCL3 is 137.33 g/mol
Here we have to get the 
of the reaction at 520 K temperature.
The of the reaction is 1.705 atm
We know the relation between and 
is 
, where = The equilibrium constant of the reaction in terms of partial pressure, = The equilibrium constant of the reaction in terms of concentration and N = number of moles of gaseous products - Number of moles of gaseous reactants.
Now in this reaction, PCl₃ + Cl₂ ⇄ PCl₅
Thus number of moles of gaseous product is 1, and number of moles of gaseous reactants are 2. Thus N = |1 - 2| = 1 mole
The given value of is 4.0×10⁻²
The molar gas constant, R = 0.082 L. Atm. mol⁻¹. K⁻¹ and temperature, T = 520 K.
On plugging the values in the equation we get,
Or, = 1.705 atm
Thus, the of the reaction is 1.705 atm
