STP is the abbreviation of standard condition for temperature and pressure which is 273.15K temperature and 1.013× 10^5 Pa pressure. Since the pressure and temperature changes, I assume the question would ask about the result of the volume. The temperature used in ideal gas should be Kelvin, so 27 Celcius would be 300.15K.
The calculation would be
PV=T
V=T/P
V2/V1= T2*P1/T1*P2
V2/V1=273.15K* 90^10^3Pa/ 300.15K * 1.013× 10^5 Pa
V2= 0.81904 * 51.7ml
V2= 42.34ml
In order to determine, Order of reaction, we have to add all the exponents written in the Chemical form, on the Reactant species.
Hope this helps!
Answer:

Explanation:
I am assuming that we have to balance this equation. On the left side, we have one Fe, 2 H, 2 Cl, and 1 S. On the right side, we have 1 Fe, 1 H, 1 Cl, and 1 S. Adding a 2 as a coefficient in front of the HCl on the right side will make 2 H and 2 Cl instead, balancing the overall equation.