What is the electron configuration for vanadium (V)? The Periodic Table A. 1s22s22p63s23p64s24d3 B. 1s22s22p63s23p63d5 C. 1s22s2
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Answer : The concentration of solution is, 8.53 M.
Explanation :
As we are given, 45.0 mass % solution of ethanol in water that means 45.0 g of ethanol present in 100 g of solution.
First we have to calculate the volume of solution.
Now we have to calculate the molarity of solution.
Mass of = 45.0 g
Volume of solution = 114.5 mL
Molar mass of = 46.07 g/mole
Molarity : It is defined as the number of moles of solute present in one liter of volume of solution.
Formula used :
Now put all the given values in this formula, we get:
Therefore, the concentration of solution is, 8.53 M.
Answer :
The correct answer for primary component of phosphate buffer at pH = 7.4 is H₂PO₄⁻ and HPO₄²⁻ .
<u>Buffer solution :</u>
It is a solution of mixture of weak acid and its conjugate base OR weak base and its conjugate acid . It resist any change in solution when small amount of strong acid or base is added .
<u>Capacity of a good buffer : </u>
A good buffer is identified when pH = pKa .
From Hasselbalch - Henderson equation which is as follows :
If [A⁻] = [HA] ,
pH = pka + log 1
pH = pKa
This determines that if concentration of weak acid and its conjugate base are changed in small quantity , the capacity of buffer to maintain a constant pH is greatest at pka . If the amount of [A⁻] or [HA] is changed in large amount , the log value deviates more than +/- 1M and hence pH .
Hence Buffer has best capacity at pH = pka .
<u>Phosphate Buffer : </u>
Phosphate may have three types of acid-base pairs at different pka ( shown in image ).
Since the question is asking the pH = 7.4
At pH = 7.4 , the best phosphate buffer will have pka near to 7.4 .
If image is checked the acid - base pair " H₂PO₄⁻ and HPO₄²⁻ has pka 7.2 which is near to pH = 7.4 .
Hence we can say , the primary chemical component of phosphate buffer at pH = 7.4 is H₂PO₄⁻ and HPO₄²⁻ .
