The change in the standard Gibbs free energy (ΔGº) for the dissociation of nitrous acid (HNO2) at 298 K is 19.09 kJ. If the pH of the solution after equilibrium is reached is 1.30 and the NO2 – concentration at equilibrium is 0.00060 M. What is the equilibrium concentration of HNO2? Hint: Use pH to determine the equilibrium concentration of H+ .
HNO2(aq) H + (aq) + NO2 – (aq)
<span>Mg(ClO2)2 has an atom of magnesium, 2 moles of chlorine and 4 moles of oxygen. </span><span>Al(ClO2)3, on the other hand, is composed of one mole of aluminum, one mole of chlorine and six moles of oxygen. The number of molecules of both is equal to 6.022 x10^23 molecules per mole of the compound.</span>
Answer:
qualitative data
and
quanitative data
Explanation:
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Part A
75.0 mL of 0.10 M HF; 55.0 mL of 0.15 M NaF
This combination will form a buffer.
Explanation
Here, weak acid HF and its conjugate base F- is available in the solution
Part B
150.0 mL of 0.10 M HF; 135.0 mL of 0.175 M HCl
This combination cannot form a buffer.
Explanation
Here, moles of HF = 0.15 x 0.1 = 0.015 moles
Moles of HCl = 0.135 x 0.175 = 0.023
Since HCl is a strong acid and the number of HCl is higher than HF. This prevents the dissociation of HF and the conjugate base F- will not be available in the solution
Part C
165.0 mL of 0.10 M HF; 135.0 mL of 0.050 M KOH
This combination will form a buffer.
Explanation
Moles of HF = 0.165 x 0.1 = 0.0165 moles
Moles of KOH = 0.135 x 0.05 = 0.00675 moles
Moles of KOH is not sufficient for the complete neutralization of HF. Thus weak acid HF and its conjugate base F- is available in the solution and form a buffer
Part D
125.0 mL of 0.15 M CH3NH2; 120.0 mL of 0.25 M CH3NH3Cl
This combination will form a buffer
Explanation
Here, weak acid CH3NH3+ and its conjugate base CH3NH2 is available in the solution and form a buffer
Part E
105.0 mL of 0.15 M CH3NH2; 95.0 mL of 0.10 M HCl
This combination will form a buffer
Explanation
Moles of CH3NH2 = 0.105 x 0.15 = 0.01575 moles
Moles of HCl = 0.095 x 0.1 = 0.0095 moles
Thus the HCl completely reacts with CH3NH2 and converts a part of the CH3NH2 to CH3NH3+. This results weak acid CH3NH3+ and its conjugate base CH3NH2 is in the solution and form a buffer
