Treatment of gamma-pyran with the hydride (h-) acceptor triphenylmethyl perchlorate gives triphenylmethane and the perchlorate s
alt a, c5h5clo5. draw the cation of a as its most stable resonance form.
1 answer:
I have provided two images to help with this question. The first image is the reaction that is taking place. The γ-pyran is treated with the hydride acceptor triphenylmethyl perchlorate. A hydride is a hydrogen atom containing a lone pair of electrons giving it a negative charge. The triphenylmethyl cation is a positively charged carbocation that greatly wants to accept an electron pair to stabilize its charge. Therefore, it abstracts a hydride from the γ-puran starting material. It grabs one of the hydrogen atoms that is drawn in the reaction scheme. This results in the formation of triphenylmethane and a pyrylium perchlorate salt with the formula C₅H₅ClO₅. The important aspect of the structure is shown in the attached images. The most stable resonance form of the pyrylium cation is shown with a positive charge on the oxygen.
The reason this pyrylium ion is the most stable resonance form is because the formation of the oxonium ion (positive charged oxygen with 3 bonds) leads to an aromatic compound. There are 6 pi electrons in conjugation in this ring similar to a benzene ring and this results in the most stable structure.
The reason this pyrylium ion is the most stable resonance form is because the formation of the oxonium ion (positive charged oxygen with 3 bonds) leads to an aromatic compound. There are 6 pi electrons in conjugation in this ring similar to a benzene ring and this results in the most stable structure.
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Explanation:
Atomic number is defined as the number of an element which represents total number of protons.
When an atom is neutral then it means it contains same number of protons and electrons.
On the other hand, atomic mass is defined as the sum of total number of protons and neutrons present in an atom.
Protons of every element remains fixed because it shows the identity of each element but if we change the number of neutrons then also identity of the atom will remain fixed. This is because changing the number of neutrons will not show any change in number of protons.
For example, and
are isotopes of hydrogen and they have same number of protons but different number of neutrons.
Thus, we can conclude that number of neutrons can vary without changing the identity of the element.