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blagie [28]
4 years ago
13

A 1.60 mole sample of carbon dioxide, for which CP,m=37.1J⋅K−1⋅mol−1 at 298 K, is expanded reversibly and adiabatically from a v

olume of 3.45 L and a temperature of 298 K to a final volume of 47.0 L. Calculate the final temperature, q, w,DeltaH and DeltaU. Assume that Cp,m is constant over the temperature interval. (Show all work)

Chemistry
1 answer:
Lapatulllka [165]4 years ago
6 0

Answer:

Final Temperature = 140.09K

q = 0 (Adiabatic process)

w = 7272.95J

DeltaH = -9.37KJ

DeltaU = -7272.95J

Explanation:

The detailed mathematical derivation from the first principle, and the appropriate substitution is as shown in the attached file.

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Which of the following compounds' solubility will not be affected by a low pH in solution?
Whitepunk [10]

The compound solubility which will not be affected by a low pH in solution is AgBr.

<h3>What is pH?</h3>

pH is a measure of the acidity or basicity of any solution and according to the pH scale 0 to 6.9 shows the acidity, 7 is neutral and 7.1 to 14 shows the basicity of any solution.

  • AgBr is sparingly soluble in water and not soluble in acids, so if we low the pH of the solution towards the acidity its solubility not affected.
  • NiCO₃ is a basic salt and and shows solubility in the acidic medium so change in pH will affect its solubility.
  • Co(OH)₂ it is also a basic compound and shows its solubility in the acidic medium and get affected when change in pH takes place.
  • PbF₂ is a strong base and also shows solubility in the acidic medium easily, so get affected when change in pH takes place.
  • In CuS, sulphide is basic ion and whole compound shows solubility in the acidic medium and get affected when low pH of solution takes place.

AgBr is not affected by a low pH in solution.

To know more about solubility, visit the below link:

brainly.com/question/23946616

3 0
2 years ago
Read 2 more answers
An oxide of aluminum contains 0.545 g of Al and 0.485 g of O. Find the empirical formula
uysha [10]

Answer:

The answer is: <u>Al2O3</u>

Explanation:

The data they give us is:

  • 0.545 gr Al
  • 0.485 gr O.

To find the empirical formula without knowing the grams of the compound, we find it per mole:

  • 0.545 g Al * 1 mol Al / 27 g Al = 0.02 mol Al
  • 0.485 g O * 1 mol O / 16 g O = 0.03 mol O

Then we must divide the results obtained by the lowest result, which in this case is 0.02:

  • 0.02 mol Al / 0.02 = 1  Al
  • 0.03 mol O / 0.02 = 1.5  O

Since both numbers have to give an integer, multiply by 2 until both remain integers:

  • 1Al * 2 = 2Al
  • 1.5O * 2 = 3O

Now the answer is given correctly:

  • Al2O3

8 0
3 years ago
A saturated solution of manganese(II) hydroxide was prepared, and an acid–base titration was performed to determine its KspKsp a
trapecia [35]

Answer:

10.945 x 10^-4

Explanation:

Balanced equation:

Mn(OH)2 +  2 HCl  -->  MnCl2  +  H2O

it takes 2 moles HCL for each mole Mn(OH)2

Next find the molarity of the Mn(OH)2 solution

= (1 mole Mn(OH)2 / 2 mole HCl)  X (0.0020 mole HCl / 1000ml) X (4.86 ml)    

= 4.86 x 10^-3 mole  

this is now dissolved in (70 + 4.86)  =  74.86 ml or 0.07486 L

thus [Mn(OH)2]  =  4.86 x 10^-3 mole / 0.07486 L  =  0.064921 M

Ksp =  [Mn2+][OH-]^2  =  4x^3  =  4(0.064921)^3  = 10.945 x 10^-4

6 0
3 years ago
Bob measured out 1.60 grams of sodium. He calculates that 1.60 g of
saul85 [17]

Answer:

84.8%

Explanation:

Step 1: Given data

Bob measured out 1.60 g of Na. He forms NaCl according to the following equation.

Na + 1/2 Cl₂ ⇒ NaCl

According to this equation, he calculates that 1.60 g of sodium should produce 4.07 g of NaCl, which is the theoretical yield. However, he carries out the experiment and only makes 3.45 g of NaCl, which is the real yield.

Step 2: Calculate the percent yield.

We will use the following expression.

%yield = real yield / theoretical yield × 100%

%yield = 3.45 g / 4.07 g × 100% = 84.8%

6 0
3 years ago
The pKa of chloroacetic acid is 2.9. If an organic chemist has a 0.10 M aqueous solution of chloroacetic acid at pH 2.4, what pe
Trava [24]

Answer:

The answer is given below.

Explanation:

We will consider the acid as HA and will set up an ICE table with the equilibrium dissociation of α.

AT pH 2.4 the initial H+ concentration will be 3.98^10-3 M

                      HA →              H+         +      A-

Initial concentration:  0.1    →  3.98 ^10-3       +      0

equilibrium concentration:  0.1(1-α) →   3.98 * 10-3 + 0.1α              0.1α

pKa of chloroacetic acid is 2.9

-log(Ka) = 2.9

Ka = 1.26 * 10-3

From the equation, Ka = [H+] * [A-] / [HA]

1.26 * 10-3 = (3.98 * 10-3 + 0.1α )* 0.1α / 0.1(1-α)      

Since α<<1, we assume 1-α = 1

Solving the equation, we have: α = 0.094

Since this is the fraction of acid that has dissociated, we can say that % of base form = 100 * α= 9.4%

6 0
3 years ago
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