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ad-work [718]
2 years ago
11

Which of these elements has the lowest melting point? (1) Li (3) K (2) Na (4) Rb

Chemistry
2 answers:
siniylev [52]2 years ago
4 0
The answer is (4) Rb. From observation, we can find that these four elements are from first column. The melting point from top to the bottom is from high to low. So the answer is (4).
natali 33 [55]2 years ago
4 0

Answer: Option (4) is the correct answer.

Explanation:

It is known that on moving down a group there will be decrease in melting point of the element because of increase in number of shells.

As a result, outermost electrons move away from the nucleus due to which there will be decrease in force of attraction between the protons and valence electrons. Hence, there will be decrease in melting point.

Therefore, the given elements are of same group and Rb has largest atomic size.

Thus, we can conclude that Rb has the lowest melting point.

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3 years ago
One mole of a monatomic ideal gas is subjected to the following sequence of steps: a. Starting at 300 K and 10 atm, the gas expa
Verdich [7]

Answer:

a) Q = 0; W = 0; ΔU = 0; ΔH = 0; ΔS = 0.09 atm.L/K

b) Q = 1250 J; W = 0; ΔU = 1250 J; ΔH = 1250 J; ΔS = -0.0235 atm.L/K

c) Q = 3653.545 J; W = - 3653.545 J; ΔU = 0; ΔH = 0; ΔS = - 3653.545 J

d) Q = - 2080 J; W = 830 J; ΔU = - 1250 J; ΔH = - 2080 J; ΔS = - 5.984 J/K

Explanation:

a) If there is a vacuum, the work is zero, as it is a free expansion, the volume increases, the pressure decreases, the temperature is constant and the internal energy is constant.

∴ n = 1 mole

∴ PV = RTn....ideal gas

∴ P1 = 10 atm

∴ R = 0.082 atm.L/K.mol

∴ T = 300 K = T2

∴ V2 = 3*V1

⇒ W = 0.....expands freely into vacuum

⇒ ΔU = Q = 0....first law

⇒ ΔS = -  nR Ln(P2/P1).....ideal gas

∴ V1*P1/T1 = V2*P2/T2

∴ T1 = T2 = 300 K

⇒ P2 = V1*P1 / V2 = V1*P1 / 3V1 = 10 atm/3 = 3.33 atm

⇒ ΔS = - (1mol)*(0.082 atm.L/K.mol) Ln ( 3.33/10)

⇒ ΔS = 0.09 atm.L/K

∴ ΔH = ΔU + (P2V2 - P1V1) = 0 + 0 = 0

b) heated reversibly at constant volume:

⇒ W = 0 ...at constant volume

∴ T2 = 400 K; T1 = 300 K

∴ V1 = V2

⇒ Q = ΔU = CvΔT....first law

∴ Cv = 12.5 J/K.mol.....monoatomic ideal gas

∴ ΔT = 400 - 300 = 100 K

⇒ Q = ΔU = 12.5 J/mol.K * 100K = 1250 J/mol * 1 mol = 1250 J

∴ ΔH = ΔU + PΔV = ΔU + 0 = 1250 J

∴ ΔS = - nR Ln (P2/P1)

∴ P2/T2 = P1/T1...constant volume

∴ P1 = 3.33 atm

⇒ P2 = P1*T2 / T1 = (3.33 atm)*(400K) / (300K) = 4.44 atm

⇒ ΔS = - (1mol)*(0.082atm.L/K.mol) Ln (4.44/3.33)

⇒ ΔS = - 0.0235 atm.L/K

c) reversibly expanded at constant temperature:

∴ T1 = T2 = 400K

∴ V2 = 3*V1

∴ ΔU = 0...constant temperature

⇒ Q = - W....fisrt law

∴ W = - ∫ PdV..... reversibly expansion

∴ P = nRT/V... ideal gas

⇒ W = - nRT ∫ dV/V

⇒ W = - nRT Ln (V2/V1)

⇒ W = - (1mol)*(8.314 J/K.mol) Ln (3)

⇒ W = - 9.134 J/K *400K = - 3653.545 J

⇒ Q = - W = 3653.545 J

⇒ ΔH = ΔU + P1V1 - P2V2 = 0 + nRT1 - nRT2 = 0 + 0 = 0

∴ ΔS = - nR Ln(P2/P1)

∴ P1 = 4.44 atm

⇒ P2 = V1*P1*T2/ V2*T1 = V1*(4.44atm)*(400K) / (3.V1)*(400K)

⇒ P2 = 4.44atm/3 = 1.48 atm

⇒ ΔS = - (1mol)*(8.314 J/mol.K) Ln (1.48/4.44)

⇒ ΔS = -9.134J/K * 400K = - 3653.545 J

d) reversibly cooled at constant pressure:

∴ T2 = 300 K;  T1 = 400 K

∴ P2 = P1

⇒ Q = ΔH = CpΔT

∴ Cp = 20.8 J/K.mol

∴ ΔT = 300 - 400 = - 100 K

⇒ Q = ΔH = 20.8 J/mol.K * ( -100K) = - 2080 J/mol * 1mol = - 2080 J

⇒ ΔU = nCvΔT = (1mol)*(12.5 J/mol.K)*( - 100K) = -1250 J

⇒ W = ΔU - Q = ΔU - ΔH = -1250 J - ( - 2080 J ) = 830 J

∴ ΔS = ∫ δQ/T = ∫ nCpdT/T

⇒ ΔS = nCp Ln (T2/T1)

⇒ ΔS = (1mol)*(20.8 J/mol.K) Ln (300/400) = - 5.984 J/K

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3 years ago
How do calculate the molar mass
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Answer:

To calculate the molar mass of a compound with multiple atoms, sum all the atomic mass of the constituent atoms molar mass can also be calculated by multiplying the atomic mass in amu by the molar mass constant (1 g/mol).

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Consider this chemical reaction, where moving from left to right represents moving forward in time. A five panel comic strip. In
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Answer:

The reaction reaches equilibrium at the fourth panel.

Explanation:

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The point where equilibrium is achieved is when exactly when we reach the panel where the spheres that make up this panel is the same as the next panel and the next, that is, the specific colour and number of spheres start to become unchanged.

And from the description given in the question,

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- In the fifth panel, there are four large red spheres and six small blue spheres.

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Hence, equilibrium is first reached at the fourth panel.

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