Answer:
Option C
CH₃CH₂CH₂COOH
Explanation:
Carbonxylic acids are compounds which has the general formula
R–COOH where R is an alkyl group.
Considering the options given in the question above,
For A:
CH₃CH₂OCH₂CH₃ is an ether compound with general formula ROR' where R and R' are both alkyl group.
For B:
CH₃CH₂CH₂CH₂OH is an alcohol with general formula ROH where R is an alkyl group.
For C:
CH₃CH₂CH₂COOH is a carbonxylic acid with general formula R–COOH where R is an alkyl group.
For D:
CH₃CH₂C=OCH₂CH₃ is a ketone compound with general formula RC=OR' where R and R' are both alkyl group
For E:
ClCH₂CH₂CH₂CH₂CH₂CH₂Br is simply an Alkyl halide with general formula XRX where X is an halogen (i.e F, Cl, Br or I) and R is an alkyl group.
From the above illustration, only option C contains a Carbonxylic compound.
Answer:
5-chloro-2-methylcyclohexanol
Explanation:
There is no structure for the compound, but we can analyze the proposed options using the IUPAC rules to name organic compounds.
IUPAC rules state that to name an organic compound, first we have to identify the priorities for the functional groups present in the compound. <em><u>In this case, the priority functional group is the alcohol group</u></em>, <u><em>so we will start the counting of the carbons in this group.</em></u> Then, the counting of carbon atoms is followed by the next substituents so they have the lowest possible numbers, <em><u>in this case, we can assign the number 2 to the methyl group and 5 to the chloride group</u></em>, and name the compound in alphabetical order, using commas to separate the words from the numbers and with no space between the words.
Since the other options involve: <u>high countings for the susbtituents groups (</u><u>3</u><u>-chloro-</u><u>6</u><u>-methylcyclohexanol)</u>, <u>wrong assignation of priority functional group (</u><u>1-chloro</u><u>-4-methylcyclohexanol), wrong sequence of counting in the compound (</u><u>2-methyl-3-chloro</u><u>cyclohexanol) and no alphabetical order to name the compound (2-</u><u>methyl</u><u>-5-</u><u>chloro</u><u>cyclohexanol), </u><u>the correct option is:</u>
5-chloro-2-methylcyclohexanol
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Answer:
A reaction is non-spontaneous at any temperature when the Gibbs free energy > 0.
Explanation:
There is a state function, that determines if a reaction is sponaneous or non spontaneous:
ΔG = Gibbs free energy
A reaction is non spontaneous when it does require energy to produce that reaction. It will be spontaneous, when the reaction does not require energy to be occured.
The formula is: ΔG = ΔH - T.ΔS
ΔH → Enthalpy → Energy gained or realeased as heat.
ΔH < 0 → <em>Exothermic reaction. Spontaneity is favored
</em>
T → Temperature
ΔS → Entropy → Degree of disorder of a system.
When the system has a considered disorder ΔS > 0, disorder increases.
When the system is more ordered, ΔS < 0, disorder decreases.
The reaction will be non spontaneous if, the enthalpy is positive (endothermic reaction) and the ΔS < 0 (disorder decreases). It will not occur if we do not give energy.
ΔG < 0 → Spontaneous reaction
ΔG > 0 → Non spontaneous reaction
ΔG = 0 → System in equilibrium
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