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GREYUIT [131]
3 years ago
9

A volume of 90.0 mLmL of aqueous potassium hydroxide (KOHKOH) was titrated against a standard solution of sulfuric acid (H2SO4H2

SO4). What was the molarity of the KOHKOH solution if 24.7 mLmL of 1.50 MM H2SO4H2SO4 was needed
Chemistry
1 answer:
Alja [10]3 years ago
7 0

Answer:

0.823 M was the molarity of the KOH solution.

Explanation:

H_2SO_4+KOH\rightarrow K_2SO_4+2H_2O (Neutralization reaction)

To calculate the concentration of base , we use the equation given by neutralization reaction:

n_1M_1V_1=n_2M_2V_2

where,

n_1,M_1\text{ and }V_1 are the n-factor, molarity and volume of acid which is H_2SO_4

n_2,M_2\text{ and }V_2 are the n-factor, molarity and volume of base which is KOH.

We are given:

n_1=2\\M_1=1.50 M\\V_1=24.7 mL\\n_2=1\\M_2=?\\V_2=90.0 mL

Putting values in above equation, we get:

2\times \1.50 M\times 24.7 mL=1\times M_2\times 90.0 mL

M_2=\frac{2\times 1.50M\times 24.7 mL}{1\times 90.0 mL}=0.823 M

0.823 M was the molarity of the KOH solution.

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) Do you think the pH of 1,0 M tri-methyl ammonium (CH3)3NH+, pKa = 9.80, will be higher or lower than that of 1.0 M phenol, C6H
Elanso [62]

Answer:

1. The pH of 1.0 M trimethyl ammonium (pH = 1.01) is lower than the pH of 0.1 M phenol (5.00).

2. The difference in pH values is 4.95.

Explanation:

1. The pH of a compound can be found using the following equation:

pH = -log([H_{3}O^{+}])

First, we need to find [H₃O⁺] for trimethyl ammonium and for phenol.

<u>Trimethyl ammonium</u>:

We can calculate [H₃O⁺] using the Ka as follows:

(CH₃)₃NH⁺ + H₂O  →  (CH₃)₃N + H₃O⁺    

1.0 - x                               x           x  

Ka = \frac{[(CH_{3})_{3}N][H_{3}O^{+}]}{[(CH_{3})_{3}NH^{+}]}

10^{-pKa} = \frac{x*x}{1.0 - x}

10^{-9.80}(1.0 - x) - x^{2} = 0    

By solving the above equation for x we have:  

x = 0.097 = [H₃O⁺]

pH = -log([H_{3}O^{+}]) = -log(0.097) = 1.01                                      

<u>Phenol</u>:

C₆H₅OH + H₂O → C₆H₅O⁻ + H₃O⁺

1.0 - x                        x             x

Ka = \frac{[C_{6}H_{5}O^{-}][H_{3}O^{+}]}{[C_{6}H_{5}OH]}

10^{-10} = \frac{x^{2}}{1.0 - x}

1.0 \cdot 10^{-10}(1.0 - x) - x^{2} = 0

Solving the above equation for x we have:

x = 9.96x10⁻⁶ = [H₃O⁺]

pH = -log([H_{3}O^{+}]) = -log(9.99 \cdot 10^{-6}) = 5.00

Hence, the pH of 1.0 M trimethyl ammonium is lower than the pH of 0.1 M phenol.

2. The difference in pH values for the two acids is:

\Delta pH = pH_{C_{6}H_{5}OH} - pH_{(CH_{3})_{3}NH^{+}} = 5.00 - 1.01 = 4.95

Therefore, the difference in pH values is 4.95.

I hope it helps you!

7 0
4 years ago
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