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andrezito [222]
3 years ago
13

Which best explains what happens when an electron moves from an excited state to the ground state? The electron absorbs energy a

s it moves to a lower energy level. The electron absorbs energy as it moves to a higher energy level. The electron releases energy as it moves to a higher energy level. The electron releases energy as it moves to a lower energy level. ANSWER IS : The electron releases energy as it moves to a lower energy level.
Chemistry
1 answer:
Papessa [141]3 years ago
8 0

Answer and

Explanation

I believe the correct answer would be the last option. When an electrons moves from an excited state to the ground state, it would release energy. An electron in the excited state would mean that it contains high kinetic energy so to move to a lower state some of these energy should be released.

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(3) A 10.00-mL sample of 0.1000 M KH2PO4 was titrated with 0.1000 M HCl Ka for phosphoric acid (H3PO4): Ka1= 7.50x10-3; Ka2=6.20
shtirl [24]

Answer:

The pH of this solution is 1,350

Explanation:

The phosphoric acid (H₃PO₄) has three acid dissociation constants:

HPO₄²⁻ ⇄ PO4³⁻ + H⁺        Kₐ₃ = 4,20x10⁻¹⁰  (1)

H₂PO₄⁻ ⇄ HPO4²⁻ + H⁺    Kₐ₂ = 6,20x10⁻⁸   (2)

H₃PO₄ ⇄ H₂PO4⁻ + H⁺       Kₐ₁ = 7,50x10⁻³   (3)

The problem says that you have 10,00 mL of KH₂PO₄ (It means H₂PO₄⁻) 0,1000 M and you add 10,00 mL of HCl (Source of H⁺) 0,1000 M. So you can see that we have the reactives of the equation (3).

We need to know what is the concentration of H⁺ for calculate the pH.

The moles of H₂PO₄⁻ are:

10,00 mL × ( 1x10⁻⁴ mol / mL) = 1x10⁻³ mol

The moles of H⁺ are, in the same way:

10,00 mL × ( 1x10⁻⁴ mol / mL) = 1x10⁻³ mol

So:

H₃PO₄   ⇄      H₂PO4⁻         +        H⁺           Kₐ₁ = 7,50x10⁻³   (3)

X mol     ⇄  (1x10⁻³-X) mol  + (1x10⁻³-X) mol                            (4)

The chemical equilibrium equation is:

Kₐ₁ = ([H₂PO4⁻] × [H⁺] / [H₃PO₄]

So:

7,50x10⁻³ = (1x10⁻³-X)² / X

Solving the equation you will obtain:

X² - 9,5x10⁻³ X + 1x10⁻⁶ = 0

Solving the quadratic formula you obtain two roots:

X = 9,393x10⁻³ ⇒ This one has no chemical logic because solving (4) you will obtain negative H₂PO4⁻ and H⁺ moles

X = 1,065x10⁻⁴

So the moles of H⁺ are : 1x10⁻³- 1,065x10⁻⁴ : 8,935x10⁻⁴ mol

The reaction volume are 20,00 mL (10,00 from both KH₂PO₄ and HCL)

Thus, the molarity of H⁺ ([H⁺]) is: 8,935x10⁻⁴ mol / 0,02000 L = 4,468x10⁻² M

pH is -log [H⁺]. So the obtained pH is 1,350

I hope it helps!

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State the difference between sugar in water and pebbles in water
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How many Joules are released to cool 250.0 grams of liquid water from 100°C to 0°C? The specific heat of water is 4.180 J/g.C.
nlexa [21]

\bold{\huge{\orange{\underline{ Solution}}}}

\bold{\underline{ Given :- }}

  • <u>We </u><u>have </u><u>250g </u><u>of </u><u>liquid </u><u>water </u><u>and </u><u>it </u><u>needs </u><u>to </u><u>be </u><u>cool </u><u>at </u><u>temperature </u><u>from </u><u>1</u><u>0</u><u>0</u><u>°</u><u> </u><u>C </u><u>to </u><u>0</u><u>°</u><u> </u><u>C</u>
  • <u>Specific </u><u>heat </u><u>of </u><u>water </u><u>is </u><u>4</u><u>.</u><u>1</u><u>8</u><u>0</u><u>J</u><u>/</u><u>g</u><u>°</u><u>C</u>

\bold{\underline{ To \: Find :- }}

  • <u>We </u><u>have </u><u>to </u><u>find </u><u>the</u><u> </u><u>total</u><u> </u><u>number </u><u>of </u><u>joules </u><u>released</u><u>. </u>

\bold{\underline{ Let's \:Begin:- }}

<u>We </u><u>know </u><u>that</u><u>, </u>

Amount of heat energy = mass * specific heat * change in temperature

<u>That </u><u>is, </u>

\sf{\red{ Q = mcΔT }}

<u>Subsitute </u><u>the </u><u>required </u><u>values </u><u>in </u><u>the </u><u>above </u><u>formula </u><u>:</u><u>-</u>

\sf{ Q = 250 × 4.180 ×(0 - 100 )}

\sf{ Q = 250 × 4.180 × - 100 }

\sf{ Q = 250 × - 418}

\sf{\pink{ Q = - 104,500 J }}

Hence, 104,500 J of heat is released to cool 250 grams of liquid water from 100° C to 0° C.

\bold{\underline{ Now :- }}

<u>We </u><u>have </u><u>to </u><u>tell </u><u>whether </u><u>the </u><u>above </u><u>process </u><u>is </u><u>endothermic </u><u>or </u><u>exothermic </u><u>:</u><u>-</u>

Here, In the above process ΔT is negative and as a result of it Q is also negative that means above process is Exothermic

  • <u>Exothermic </u><u>process </u><u>:</u><u>-</u><u> </u><u>It </u><u>is </u><u>the </u><u>process </u><u>in </u><u>which </u><u>heat </u><u>is </u><u>evolved </u><u>. </u>
  • <u>Endothermic </u><u>process </u><u>:</u><u>-</u><u> </u><u>It </u><u>is </u><u>the </u><u>process </u><u>in </u><u>which </u><u>heat </u><u>is </u><u>absorbed </u><u>.</u>
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