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Answer:
3,964 years.
Explanation:
- It is known that the decay of a radioactive isotope isotope obeys first order kinetics.
- Half-life time is the time needed for the reactants to be in its half concentration.
- If reactant has initial concentration [A₀], after half-life time its concentration will be ([A₀]/2).
- Also, it is clear that in first order decay the half-life time is independent of the initial concentration.
- The half-life of the element is 5,730 years.
- For, first order reactions:
<em>k = ln(2)/(t1/2) = 0.693/(t1/2).</em>
Where, k is the rate constant of the reaction.
t1/2 is the half-life of the reaction.
∴ k =0.693/(t1/2) = 0.693/(5,730 years) = 1.21 x 10⁻⁴ year⁻¹.
- Also, we have the integral law of first order reaction:
<em>kt = ln([A₀]/[A]),</em>
where, k is the rate constant of the reaction (k = 1.21 x 10⁻⁴ year⁻¹).
t is the time of the reaction (t = ??? year).
[A₀] is the initial concentration of the sample ([A₀] = 100%).
[A] is the remaining concentration of the sample ([A] = 61.9%).
∴ t = (1/k) ln([A₀]/[A]) = (1/1.21 x 10⁻⁴ year⁻¹) ln(100%/61.9%) = 3,964 years.
Complete Question
49.9 ml of a 0.00292 m stock solution of a certain dye is diluted to 1.00 L. the diluted solution has an absorbance of 0.600. what is the molar absorptivity coefficient of the dye
Answer:
The value is 
Explanation:
From the question we are told that
The volume of the stock solution is 
The concentration of the stock solution is 
The volume of the diluted solution is 
The absorbance is 
Generally the from the titration equation we have that
=> 
=> 
Generally from Beer's law we have that
=> 
Here l is the length who value is 1 cm because the unit of molar absorptivity coefficient of the dye is 
So
=>
