To find - Identify what kind of ligand (weak or strong), what kind
of wavelength (long or short), what kind of spin (high spin or
low spin) and whether it is paramagnetic or diamagnetic for
the following complexes.
1. [Mn(CN)6]4-
2. [Fe(OH)(H2O)5]2
3. [CrCl4Br2]3-
Step - by - Step Explanation -
1.
[Mn(CN)⁶]⁴⁻ :
Ligand - Strong
Wavelength - Short
Spin - Low spin
Number of unpaired electrons = 1 ∴ paramagnetic.
2.
[Fe(OH)(H₂O)₅]²⁺ :
Ligand - Weak ( both OH⁻ and H₂O )
Wavelength - Long
Spin - High spin
Number of unpaired electrons = 5 ∴ paramagnetic.
3.
[CrCl₄Br₂]³⁻ :
Ligand - Weak ( both Br⁻ and Cl⁻ )
Wavelength - Long
Spin - High spin
Number of unpaired electrons = 3 ∴ paramagnetic.
Soap is the sodium or potassium salt of long chain of fatty acid. Fatty acids when treated with NaOH or KOH forms Soap. This process is called as Saponification. Examples of Soap are as follow,
1. Sodium Stearate C₁₇H₃₅COONa
2. Potassium Oleate C₁₇H₃₃COOK
Reaction of Soap with MgCl₂;
When Soap is treated with MgCl₂ or CaCl₂ it forms insoluble precipitate called S.C.U.M. The reactions with MgCl₂ are as follow,
2C₁₇H₃₅COONa + MgCl₂ --------> 2C₁₇H₃₅COOMg + 2 NaCl
2C₁₇H₃₃COOK + MgCl₂ --------> 2C₁₇H₃₅COOMg + 2 KCl
These reaction are often found in hard water. And this reaction decreases the effectiveness of soap.
Two electrons that are of the same charge will repel each other
The heat released by cpmolete the combustion of organic products with oxygen is called heat of combustion.
Here 1 mol of CH4 realesed 802.3 KJ
To emit 264 kJ you multiply you need (1 mol of CH4/802.3 kJ)* 264 kJ = 0.329 mol of CH4
The molar mass, MM, of CH4 is 12 g/mol + 4*1g/mol = 16 g/mol
The to obtain the mass multiply the number of moles times the molar mass:
mass = n * MM = 0.329mol * 16g/mol = 5.26 grams
Answer: 5.26 grams