Question

An electrochemical cell has the following standard cell notation: Al(s) | Al3+(aq) || Mg2+(aq) | Mg(s)

Answer 1

Answer:

a. Al(s) ⇄ Al⁺³(aq) + 3e⁻ (oxidation)

Mg²⁺(aq) + 2e⁻ ⇄ Mg(s) (reduction)

b. ΔE° = + 0.715 V

c.  It's an electrolytic cell, because it's a nonspontaneous reaction.

d. 2Al(s) + 3Mg²⁺(aq) ⇄ 2Al⁺³(aq) + 3Mg(s)

Explanation:

a. By the notation given, first is represented the oxidation reaction and then the reduction reaction, so they are:

Al(s) ⇄ Al⁺³(aq) + 3e⁻ (oxidation)

Mg²⁺(aq) + 2e⁻ ⇄ Mg(s) (reduction)

b. The standard potential of the cell (ΔE°) is the reduction potential of the oxidation less the reduction potential of the reduction. The reduction potentials are:

Al(s) = -1.66 V

Mg(s) = -2.375 V

ΔE° = -1.66 - (-2.375)

ΔE° = + 0.715 V

c. It's an electrolytic cell.

A galvanic cell is spontaneous, so the cathode (reduction) has a higher E° than the cathode (oxidation). In this case, the oxidation reaction has a higher E°, so the reaction is nonspontaneous and it's necessary an external force to it happen, so it's an electrolytic cell.

d. 2Al(s) + 3Mg²⁺(aq) ⇄ 2Al⁺³(aq) + 3Mg(s)

The number of electrons must be the same, so the oxidation reaction is multiplied by 2, and the reduction reaction by 3.