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sleet_krkn [62]
3 years ago
13

The most common form of nylon is 63.68% carbon, 9.80% hydrogen, 12.38% nitrogen and 14.14 % oxygen. Calculate the empirical form

ula for nylon.
Chemistry
1 answer:
Mashcka [7]3 years ago
5 0

Answer:

The empirical formule is C6H11NO

Explanation:

Step 1: Data given

Suppose the mass = 100 grams

Nylon contains:

63.68 % carbon = 63.68 grams

9.80 % hydrogen = 9.80 grams

12.38 % nitrogen = 12.38 grams

14.14 % oxygen = 14.14 grams  

Molar mass C = 12.01 g/mol

Molar mass H = 1.01 g/mol

Molar mass nitrogen = 14.01 g/mol

Molar mass oxygen = 16.00 g/mol

Step 2: Calculate moles

Moles = mass / moles

Moles C = 63.68 grams / 12.01 g/mol

Moles C = 5.302 moles

Moles H = 9.80 grams / 1.01 g/mol

Moles H = 9.70 moles

Moles N = 12.38 grams / 14.01 g/mol

Moles N = 0.8837 moles

Moles O = 14.14 grams / 16.00 g/mol

Moles O = 0.8838 moles

Step 3: Calculate mol ratio

We divide by the smalleste amount of moles

C: 5.302/0.8837 = 6

H: 9.70/0.8837 = 11

N: 0.8837/0.8837 = 1

O: 0.8838/0.8837 = 1

The empirical formule is C6H11NO

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Answer:

X(O₂) = 0.323

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We have the partial pressures of oxygen (O₂) and nitrogen (N₂):

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P(N₂) = 0.80 atm

In order to solve the problem, you need the solubilities of each gas in water at 298 K. We can consider 1.3 x 10⁻³ mol/(L atm) for oxygen (O₂) and 6.8 x 10⁻⁴mol/(L atm) for nitrogen (N₂) from the bibliography.

s(O₂) = 1.3 x 10⁻³ mol/(L atm)

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So, we calculate the concentration (C) of each gas as the product of its partial pressure (P) and the solubility (s):

C(O₂) = P(O₂) x s(O₂) = 0.20 atm x 1.3 x 10⁻³ mol/(L atm) = 2.6 x 10⁻⁴mol/L

C(N₂) = P(N₂) x s(N₂) = 0.80 atm x 6.8 x 10⁻⁴mol/(L atm) = 5.44 x 10⁻⁴ mol/L

In 1 liter of water, we have the following number of moles (n):

n(O₂) = 2.6 x 10⁻⁴ mol

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Thus, the total number of moles (nt) is calculated as the sum of the number of moles of the gases in the mixture:

nt = n(O₂) + n(N₂) = 2.6 x 10⁻⁴ mol + 5.44 x 10⁻⁴ mol = 8.04 x 10⁻⁴ mol

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X(O₂) = n(O₂)/nt = 2.6 x 10⁻⁴ mol/(8.04 x 10⁻⁴ mol) = 0.323

X(N₂) = n(N₂)/nt = 5.44 x 10⁻⁴ mol/(8.04 x 10⁻⁴ mol) = 0.677

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