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olga55 [171]
3 years ago
7

Consider the reaction:

Chemistry
1 answer:
stich3 [128]3 years ago
7 0

Answer:

\large \boxed{\text{-851.4 kJ/mol}}

Explanation:

2Al(s) + Fe₂O₃(s) ⟶ Al₂O₃(s) + 2Fe(s); ΔᵣH = ?

The formula for calculating the enthalpy change of a reaction by using the enthalpies of formation of reactants and products is

\Delta_{\text{r}}H^{\circ} = \sum \Delta_{\text{f}} H^{\circ} (\text{products}) - \sum\Delta_{\text{f}}H^{\circ} (\text{reactants})

                            2Al(s) + Fe₂O₃(s) ⟶ Al₂O₃(s) + 2Fe(s)

ΔfH°/kJ·mol⁻¹:         0         -824.3         -1675.7         0

\begin{array}{rcl}\Delta_{\text{r}}H^{\circ} & = & [1(-1675.7) + 2(0)] - [2(0) - 1(-824.3)]\\& = & -1675.7 + 824.3\\& = & \textbf{-851.4 kJ/mol}\\\end{array}\\\text{The enthalpy change is } \large \boxed{\textbf{-851.4 kJ/mol}}

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The reaction;
O(g) +O2(g)→O3(g), ΔH = sum of bond enthalpy of reactants-sum of food enthalpy of products.
ΔH = ( bond enthalpy of O(g)+bond enthalpy of O2 (g) - bond enthalpy of O3(g)
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Bond enthalpy (BE) of O3(g) is equals to 2× bond enthalpy of O3(g) because, O3(g) has two types of bonds from its lewis structure (0-0=0).
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