Answer:
74.4 ml
Explanation:
C₆H₈O₇(aq) + 3NaHCO₃(s) => Na₃C₆H₅O₃(aq + 3CO₂(g) + 3H₂O(l)
Given 15g = 15g/84g/mol = 0.1786mole Sodium Bicarbonate
From equation stoichiometry 3moles NaHCO₃ is needed for each mole citric acid or, moles of citric acid needed is 1/3 of moles sodium bicarbonate used.
Therefore, for complete reaction of 0.1786 mole NaHCO₃ one would need 1/3 of 0.1786 mole citric acid or 0.0595 mole H-citrate.
The question is now what volume of 0.8M H-citrate solution would contain 0.0595mole of the H-citrate? This can be determined from the equation defining molarity. That is => Molarity = moles solute / Liters of solution
=> Volume (Liters) = moles citric acid / Molarity of citric acid solution
=> Volume needed in liters = 0.0.0595 mole/0.80M = 0.0744 Liters or 74.4 ml
Redox reaction is the reduction and oxidation reaction. It is a chemical reaction that involves a transfer of electrons. It can mean loss of oxygen (oxidation) or gain of electrons (reduction). Oxydation is the process of where a sustance loses electrons, gains an oxygen atom/s, loses a hydrogen atom/s. reduction is the opposite.
In a redox reaction, one of the reactants must release electrons.
First, we should get moles acetic acid = molarity * volume
=0.3 M * 0.5 L
= 0.15 mol
then, we should get moles acetate = molarity * volume
= 0.2 M * 0.5L
= 0.1 mol
then, we have to get moles of OH- which added:
moles OH- = molarity * volume
= 1 M * 0.02L
= 0.02 mol
when the reaction equation is:
CH3COOH + OH- → CH3COO- + H2O
moles acetic acid after adding OH- = (0.15-0.02)
= 0.13M
moles acetate after adding OH- = (0.1 + 0.02)
= 0.12 M
Total volume = 0.5 L + 0.02 L= 0.52 L
∴[acetic acid] = moles acetic acid after adding OH- / total volume
= 0.13mol / 0.52L
= 0.25 M
and [acetate ) = 0.12 mol / 0.52L
= 0.23 M
by using H-H equation we can get PH:
PH = Pka + ㏒[salt/acid]
when we have Ka = 1.8 x 10^-5
∴Pka = -㏒Ka
= -㏒ 1.8 x 10^-5
= 4.7
So by substitution:
∴ PH = 4.7 + ㏒[acetate/acetic acid]
= 4.7 + ㏒(0.23/0.25)
= 4.66
Answer:
The minimum mass of ethylene glycol = 6.641 Kg
Explanation:

Where T_f = freezing point of pure solvent water, 0°C
T_f'= Freezing point of solvent after mixture
K_f = Freezing point depression constant = 1.86 °C/m
Moecular weight of ethylene glycol = 60 g/mol
Weight of ethylene glycol = 14.5 Kg= 14.5×10^3 g
molality of ethylene glycol

Substitute the values to calculate m

by formula

calculating we get w = 6641.93 g
Therefore, The minimum mass of ethylene glycol = 6.641 Kg