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Bioluminescence is a chemical reaction that takes place in a living organism when the organism emits light. Bioluminescence doesn't consume or produce heat, hence it can be neither endothermic nor exothermic reaction. It emits a heatless light not heat.
For bioluminescence, it could be said that it is an exoenergetic reaction because it uses energy from a chemical reaction to produce light.
NO₂ is a brown gas while N₂O₄ is colorless. If heating causes a brown color to persist, then this means that heating causes the reaction to shift backwards and produce NO₂. Therefore, the reaction must be exothermic.
Chemical Equation Balancer
The the last one, but isn't it c6h12o6?
