Answer:
Chemical, cause physical are changes affecting the form of a chemical substance, but not its chemical composition. This doesn't affect the substance but the composition.
Explanation:
STP is the abbreviation of standard condition for temperature and pressure which is 273.15K temperature and 1.013× 10^5 Pa pressure. Since the pressure and temperature changes, I assume the question would ask about the result of the volume. The temperature used in ideal gas should be Kelvin, so 27 Celcius would be 300.15K.
The calculation would be
PV=T
V=T/P
V2/V1= T2*P1/T1*P2
V2/V1=273.15K* 90^10^3Pa/ 300.15K * 1.013× 10^5 Pa
V2= 0.81904 * 51.7ml
V2= 42.34ml
Boiling point elevation is given as:
ΔTb=iKbm
Where,
ΔTb=elevation in the boiling point
that is given by expression:
ΔTb=Tb (solution) - Tb (pure solvent)
Here Tb (pure solvent)=118.1 °C
i for CaCO3= 2
Kb=2.93 °C/m
m=Molality of CaCO₃:
Molality of CaCO₃=Number of moles of CaCO₃/ Mass of solvent (Kg)
=(Given Mass of CaCO3/Molar mass of CaCO₃)/ Mass of solvent (Kg)
=(100.0÷100 g/mol)/0.4
= 2.5 m
So now putting value of m, i and Kb in the boiling point elevation equation we get:
ΔTb=iKbm
=2×2.93×2.5
=14.65 °C
boiling point of a solution can be calculated:
ΔTb=Tb (solution) - Tb (pure solvent)
14.65=Tb (solution)-118.1
Tb (solution)=118.1+14.65
=132.75
