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julsineya [31]
4 years ago
13

Determine the molarity for the fixer Sodium carbonate decahydrate (I dissolved 127.62 grams of sodium carbonate for every 4 lite

rs of water)
Chemistry
1 answer:
grin007 [14]4 years ago
4 0

Answer:

0.112 M.

Explanation:

  • Molarity is the no. of moles of solute in a 1.0 L of the solution.

M = n/V.

<em>M = (mass/molar mass)solute x (1000/V of the solution).</em>

mass = 127.62 g.

molar mass = 286.138 g/mol.

V of the solution = 4.0 L = 4000.0 mL.

<em>∴ M = (mass/molar mass)solute x (1000/V of the solution)</em> = (127.62 g / 286.138 g/mol) x (1000 / 4000.0 mL) = <em>0.1115 M ≅ 0.112 M.</em>

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Use the given data at 500 K to calculate ΔG°for the reaction
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Answer : The  value of \Delta G^o for the reaction is -959.1 kJ

Explanation :

The given balanced chemical reaction is,

2H_2S(g)+3O_2(g)\rightarrow 2H_2O(g)+2SO_2(g)

First we have to calculate the enthalpy of reaction (\Delta H^o).

\Delta H^o=H_f_{product}-H_f_{reactant}

\Delta H^o=[n_{H_2O}\times \Delta H_f^0_{(H_2O)}+n_{SO_2}\times \Delta H_f^0_{(SO_2)}]-[n_{H_2S}\times \Delta H_f^0_{(H_2S)}+n_{O_2}\times \Delta H_f^0_{(O_2)}]

where,

\Delta H^o = enthalpy of reaction = ?

n = number of moles

\Delta H_f^0 = standard enthalpy of formation

Now put all the given values in this expression, we get:

\Delta H^o=[2mole\times (-242kJ/mol)+2mole\times (-296.8kJ/mol)}]-[2mole\times (-21kJ/mol)+3mole\times (0kJ/mol)]

\Delta H^o=-1035.6kJ=-1035600J

conversion used : (1 kJ = 1000 J)

Now we have to calculate the entropy of reaction (\Delta S^o).

\Delta S^o=S_f_{product}-S_f_{reactant}

\Delta S^o=[n_{H_2O}\times \Delta S_f^0_{(H_2O)}+n_{SO_2}\times \Delta S_f^0_{(SO_2)}]-[n_{H_2S}\times \Delta S_f^0_{(H_2S)}+n_{O_2}\times \Delta S_f^0_{(O_2)}]

where,

\Delta S^o = entropy of reaction = ?

n = number of moles

\Delta S_f^0 = standard entropy of formation

Now put all the given values in this expression, we get:

\Delta S^o=[2mole\times (189J/K.mol)+2mole\times (248J/K.mol)}]-[2mole\times (206J/K.mol)+3mole\times (205J/K.mol)]

\Delta S^o=-153J/K

Now we have to calculate the Gibbs free energy of reaction (\Delta G^o).

As we know that,

\Delta G^o=\Delta H^o-T\Delta S^o

At room temperature, the temperature is 500 K.

\Delta G^o=(-1035600J)-(500K\times -153J/K)

\Delta G^o=-959100J=-959.1kJ

Therefore, the value of \Delta G^o for the reaction is -959.1 kJ

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3 years ago
Identify the conjugate acid/base pairs in each of the following equations:
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Answer:

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(d)  Pair 1: HNO₃ and NO₃⁻

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Explanation:

When an acid loses its proton (H⁺), a conjugate base is produced.

When a base accepts a proton (H⁺), it forms a conjugate acid.

(a) H₂S is an acid. When it loses a proton, it forms the conjugate base HS⁻.

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(b) The acid HSO₄⁻ loses a H⁺ ion and forms the conjugate base SO₄²⁻.

     The base NH₃ accepts a H⁺ ion to form the conjugate acid NH₄⁺.

(c) HBr is an acid. When loses the H⁺ ion, it forms the conjugate base Br⁻.

   CH₃O⁻ accepts a H⁺ ion to form the conjugate acid CH₃OH.

(d) HNO₃ loses a proton to form the conjugate base NO₃⁻.

    H₂O gains a proton to form the conjugate acid H₃O⁺.

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