Magnesium silicate is a compound of magnesium oxide and silicon. It is the magnesium salt of silicic acid containing an unspecified amount of water. The molecular formula can be expressed more clearly as MgSiO3.
This means a release of free energy from the system corresponds to a negative change in free energy, but to a positive change for the surroundings.
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Quantity of K2S m = 0.105 m
Number of ions i = 2(K) + 1(S) = 3
Freezing point depression constant of water Kf = 1.86
delta T = i x m x Kf = 3 x 0.105 x 1.86 = 0.586
Freezing point = 0 - 0.586 = 0.586 C
Boiling point constant of water Kb = 0.512
delta T = i x m x Kb = 3 x 0.105 x 0.512 = 0.161
Boiling point = 100 + 0.161 = 100.161 C