The functions of angles are used to find unknown lengths or angles that can't be measured, in terms of known quantities. The trig functions of angles are ratios of lengths, so they're bare naked numbers without units.
The ampere (A) is a basic SI unit consisting of the amount of electric charge or number of electrons that pass a point in a electrical circuit in one second. The volt (V) is the electrical potential causing electrons to move through a wire. It is a joule of energy per coulomb of charge.