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arsen [322]
3 years ago
10

Hydrogenation reactions are used to add hydrogen across double bonds in hydrocarbons and other organic compounds. use average bo

nd energies to calculate δhrxn for the hydrogenation reaction.
Chemistry
1 answer:
Mamont248 [21]3 years ago
7 0
H2(g) +C2H4(g)→C2H6(g)
H-H +H2C =CH2→H3C-Ch3
2C -H bonds and one C-C bond are formed while enthalpy change (dH) of the reaction,
H-H: 432kJ/mol
C=C: 614kJ/mol
C-C: 413 kJ/mol
C-C: 347 kJ/mol
dH is equal to sum of the energies released during the formation of new bonds or negative sign, and sum of energies required to break old bonds or positive sign.
The bond which breaks energy is positive.
432+614 =1046kJ/mol
Formation of bond energy is negative
2(413) + 347 = 1173 kJ/mol
dH reaction is -1173 + 1046 =-127kJ/mol 
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Answer:

a, and f.

Explanation:

To be deprotonated, the conjugate acid of the base must be weaker than the acid that will react, because the reactions favor the formation of the weakest acid. The pKa value measures the strength of the acid. As higher is the pKa value, as weak is the acid. So, let's identify the conjugate acid and their pKas:

a. NaNH2 will dissociate, and NH2 will gain the proton and forms NH3 as conjugate acid. pKa = 38.0, so it happens.

b. NaOH will dissociate, and OH will gain the proton and forms H2O as conjugate acid. pKa = 14.0, so it doesn't happen.

c. NaC≡N will dissociate, and CN will gain a proton and forms HCN as conjugate acid. pKa = 9.40, so it doesn't happen.

d. NaCH2(CO)N(CH3)2 will dissociate and forms CH3(CO)N(CH3)2 as conjugate acid. pKa = -0.19, so it doesn't happen.

e. H2O must gain one proton and forms H3O+. pKa = -1.7, so it doesn't happen.

f. CH3CH2Li will dissociate, and the acid will be CH3CH3. pKa = 50, so it happens.

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