Combustion reaction for menthol is as follows;
CxHyOz + O₂ ---> xCO₂ + H₂O
Mass of CO₂ formed - 28.16 mg
Therefore number of moles formed - 28.16/ 44 g/mol = 0.64 mmol
Mass of water formed - 11.53 mg
number of water moles formed - 11.53 mg/18 g/mol = 0.64 mmol
From CO₂,
1 mol of CO₂ - 1 mol of C and 2 mol of O
therefore number of C moles - 0.64 mmol
O moles - 1.28 mmol
from H₂O
1 mol of H₂O - 2 mol of H and 1 mol of O
number of H moles - 1.28 mmol
O moles - 0.64 mmol
Mass of menthol initially - 10 mg
in reactions, the masses of products are equal to the masses of reactants. The excess mass to the products formed is due to O₂ in air
Original mass of menthol - 10 mg
mass of water and CO₂ - 11.53 mg + 28.16 mg = 39.69
Difference in mass - 39.69 - 10 = 29.69 mg
This difference comes from O moles in air - 29.69 mg/ 16 g/mol = 1.8556 mmol
then O moles coming from menthol - (1.28 + 0.64) - 1.8556 = 0.064 mmol
In menthol
C moles - 0.64 mmol
H moles - 1.28 mmol
O moles - 0.064 mmol
ratios of C:H:O
C H O
0.64 1.28 0.064
x1000 x1000 x1000 to get whole numbers
640 1280 64
10 20 1
Simplest ratio of C:H:O is 10:20:1
therefore empirical formula of menthol is C₁₀H₂₀O
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Answer:
The reaction is exothermic
The temperature of the water bath goes up
Explanation:
An exothermic reaction is one in which energy flows out of the reaction system.
In this case, the system is the reaction vessel while the surrounding is the water bath. We see in the question that 300.1J of heat flows out of the system during the reaction. This is heat lost to the surroundings showing that the reaction is exothermic.
As energy is lost to the surroundings, the temperature of the water bath rises accordingly.
Higher. Because this type of heat transfer is conduction, meaning that heat always transfers to cooler objects.
