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Usimov [2.4K]
3 years ago
10

Given an initial cyclopropane concentration of 0.00560 m, calculate the concentration of cyclopropane that remains after 1.50 ho

urs.
Chemistry
1 answer:
maria [59]3 years ago
8 0

<span>We can solve this problem by assuming that the decay of cyclopropane follows a 1st order rate of reaction. So that the equation for decay follows the expression:</span>

A = Ao e^(- k t) 

Where,

A = amount remaining at time t = unknown (what to solve for) <span>
Ao = amount at time zero = 0.00560 M </span><span>
<span>k = rate constant
t = time = 1.50 hours or 5400 s </span></span>

The rate constant should be given in the problem which I think you forgot to include. For the sake of calculation, I will assume a rate constant which I found in other sources:

k = 5.29× 10^–4 s–1                     (plug in the correct k value)

<span>Plugging in the values in the 1st equation:</span>

A = 0.00560 M * e^(-5.29 × 10^–4 s–1 * 5400 s )

A = 3.218 <span>× 10^–4 M           (simplify as necessary)</span>

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Nickel and carbon monoxide react to form nickel carbonyl, like this: (s)(g)(g) At a certain temperature, a chemist finds that a
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The question is incomplete, here is the complete question:

Nickel and carbon monoxide react to form nickel carbonyl, like this:

Ni(s)+4CO(g)\rightarrow Ni(CO)_4(g)

At a certain temperature, a chemist finds that a 2.6 L reaction vessel containing a mixture of nickel, carbon monoxide, and nickel carbonyl at equilibrium has the following composition:

Compound            Amount

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   CO                        1.98 g

Ni(CO)_4                  0.597 g

Calculate the value of the equilibrium constant.

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<u>Explanation:</u>

We are given:

Mass of nickel = 12.7 g

Mass of CO = 1.98 g

Mass of Ni(CO)_4 = 0.597 g

Volume of container = 2.6 L

To calculate the number of moles for given molarity, we use the equation:

\text{Molarity of the solution}=\frac{\text{Given mass of solute}}{\text{Molar mass of solute}\times \text{Volume of solution (in L)}}

\text{Equilibrium concentration of nickel}=\frac{12.7}{58.7\times 2.6}=0.083M

\text{Equilibrium concentration of CO}=\frac{1.98}{28\times 2.6}=0.0272M

\text{Equilibrium concentration of }Ni(CO)_4=\frac{0.597}{170.73\times 2.6}=0.00134M

For the given chemical reaction:

Ni(s)+4CO(g)\rightarrow Ni(CO)_4(g)

The expression of equilibrium constant for the reaction:

K_{eq}=\frac{[Ni(CO)_4]}{[CO]^4}

Concentrations of pure solids and pure liquids are taken as 1 in equilibrium constant expression.

Putting values in above expression, we get:

K_{eq}=\frac{0.00134}{(0.0272)^4}\\\\K_{eq}=2448.1

Hence, the value of equilibrium constant for the reaction is 2448.1

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