Answer: Endothermic reaction
Explanation:
Exothermic reactions are defined as the reactions in which energy of the product is lesser than the energy of the reactants. The total energy is released in the form of heat and
for the reaction comes out to be negative.
Endothermic reactions are defined as the reactions in which energy of the product is greater than the energy of the reactants. The total energy is absorbed in the form of heat and
for the reaction comes out to be positive.
As the energy of reactants is 180 kJ and that of products is 300 kJ, the energy of products is greater than that of reactants, which means the energy has been absorbed and reaction is endothermic.
Answer:
Clavulanic acid has two (2) chiral centers.
Explanation:
A chiral center is a center (usually carbon) with four different substituents.
The structure of clavulanic acid is shown in the attachment below.
Consider the labeled diagram in the attachment,
Carbon A is not a chiral carbon because it has two hydrogen atoms attached to it
Carbon B is not a chiral carbon because it has only three substituents
Carbon C is a chiral carbon because it has four different substituents
Carbon D is a chiral carbon because it has four different substituents
Carbon E is not a chiral carbon because it has only three atoms directly attached to it
Carbon F is not a chiral carbon because it has only three atoms directly attached to it
Carbon G is not a chiral carbon because it has two hydrogen atoms attached to it
Carbon H is not a chiral carbon because it has only three substituents
Then, only carbons C and D are chiral carbons.
Hence, clavulanic acid have two (2) chiral centers.
ΔG⁰ = ΔH⁰ - TΔS
ΔH⁰ = Hf,(CH₃OH) - Hf,(CO) = -238.7 + 110.5 = -128.2 kJ/mol
ΔS = S(CH₃OH) - S(CO) - 2S(H₂) = 126.8 - 197.7 - 2 x 130.6 = -332.1 J/mol.K
So
ΔG⁰ = - 128200 + 332.1 T
For the reaction to be spontaneous:
ΔG⁰ < 0
So: -128200 + 332.1 T < 0
332.1 T < 128200
T < 386.028 K
Answer:
65.08 g.
Explanation:
- For the reaction, the balanced equation is:
<em>2AlCl₃ + 3Br₂ → 2AlBr₃ + 3Cl₂,</em>
2.0 mole of AlCl₃ reacts with 3.0 mole of Br₂ to produce 2.0 mole of AlBr₃ and 3.0 mole of Cl₂.
- Firstly, we need to calculate the no. of moles of 36.2 grams of AlCl₃:
<em>n = mass/molar mass</em> = (36.2 g)/(133.34 g/mol) = <em>0.2715 mol.</em>
<u><em>Using cross multiplication:</em></u>
2.0 mole of AlCl₃ reacts with → 3.0 mole of Br₂, from the stichiometry.
0.2715 mol of AlCl₃ reacts with → ??? mole of Br₂.
∴ The no. of moles of Br₂ reacts completely with 0.2715 mol (36.2 g) of AlCl₃ = (0.2715 mol)(3.0 mole)/(2.0 mole) = 0.4072 mol.
<em>∴ The mass of Br₂ reacts completely with 0.2715 mol (36.2 g) of AlCl₃ = no. of moles of Br₂ x molar mass</em> = (0.4072 mol)(159.808 g/mol
) = <em>65.08 g.</em>