The equation of state for a hypothetical ideal gas is known as the ideal gas law, sometimes known as the general gas equation. i.e. PV = nRT or P1V1 = P2V2.
- According to the ideal gas law, the sum of the absolute temperature of the gas and the universal gas constant is equal to the product of the pressure and volume of one gram of an ideal gas.
- Robert Boyle, Gay-Lussac, and Amedeo Avogadro's observational work served as the basis for the ideal gas law. The Ideal gas equation, which simultaneously describes every relationship, is obtained by combining all of their observations into a single statement.
- When applying the gas constant R = 0.082 L.atm/K.mol, pressure, volume, and temperature should all be expressed in units of atmospheres (atm), litres (L), and kelvin (K).
- At high pressure and low temperature, the ideal gas law basically fails because molecule size and intermolecular forces are no longer negligible but rather become significant considerations.
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Answer:
an atom cannot be broken down
Answer:
Change in entropy for the reaction is
ΔS° = -268.13 J/K.mol
Explanation:
To calculate the change in entropy for the balanced reaction, we require the natural entropy of all the reactants and products in the reaction.
3 NO₂(g) + H₂O(l) → 2 HNO₃(l) + NO(g)
From Literature.
S°(NO₂) = 240.06 J/K.mol
S°(H₂O) = 69.91 J/K.mol
S°(HNO₃) = 155.60 J/K.mol
S°(NO) = 210.76 J/K.mol
These are the entropies of the reactants and products under standard conditions of 298.15 K and 1 atm.
Note that
ΔS° = Σ nᵢS°(for products) - Σ nᵢS°(for reactants)
Σ nᵢS°(for products) = [2 × S°(HNO₃)] + [1 × S°(NO)]
= (2 × 155.60) + (1 × 210.76) = 521.96 J/K.mol
Σ nᵢS°(for reactants) = [3 × S°(NO₂)] + [1 × S°(H₂O)]
= (3 × 240.06) + (1 × 69.91) =790.09 J/K.mol
ΔS° = Σ nᵢS°(for products) - Σ nᵢS°(for reactants)
ΔS° = 521.96 - 790.09 = -268.13 J/K.mol
Hope this Helps!!
