Answer:
Noble gases.
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A significant MOE exists compared to developmental toxicity effect levels.
Blood alcohol levels from ABHS approximate consumption of non-alcoholic beverages.
No significant risk of developmental toxicity is expected from ABHS use.
Ethanol-based topical antiseptic hand rubs, commonly referred to as alcohol-based hand sanitizers (ABHS), are routinely used as the standard of care to reduce the presence of viable bacteria on the skin and are an important element of infection control procedures in the healthcare industry.
There are no reported indications of safety concerns associated with the use of these products in the workplace. However, the prevalence of such alcohol-based products in healthcare facilities and safety questions raised by the U.S. FDA led us to assess the potential for developmental toxicity under relevant product-use scenarios.
Estimates from a physiologically based pharmacokinetic modeling approach suggest that occupational use of alcohol-based topical antiseptics in the healthcare industry can generate low, detectable concentrations of ethanol in blood.
This unintended systemic dose probably reflects contributions from both dermal absorption and inhalation of the volatilized product.
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Answer:
Br- Withdraws electrons inductively
Donates electrons by resonance
CH2CH3 - Donates electrons by hyperconjugation
NHCH3- Withdraws electrons inductively
Donates electrons by resonance
OCH3 - Withdraws electrons inductively
Donates electrons by resonance
+N(CH3)3 - Withdraws electrons inductively
Explanation:
A chemical moiety may withdraw or donate electrons by resonance or inductive effect.
Halogens are electronegative elements hence they withdraw electrons by inductive effect. However, they also contain lone pairs so the can donate electrons by resonance.
Alkyl groups donate electrons by hyperconjugation involving hydrogen atoms.
-NHCH3 and contain species that have lone pair of electrons which can be donated by resonance. Also, the nitrogen and oxygen atoms are very electron withdrawing making the carbon atom to have a -I inductive effect.
+N(CH3)3 have no lone pair and is strongly electron withdrawing by inductive effects.
