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zvonat [6]
3 years ago
5

General Chemistry fourth edition by McQuarrie, Rock, and Gallogly. University Science Books presented by Macmillan Learning.

Chemistry
1 answer:
Helen [10]3 years ago
3 0

Answer:

3.07 Cal/g

Explanation:

Step 1: Calculate the heat absorbed by the calorimeter

We will use the following expression.

Q = C × ΔT

where,

  • Q: heat absorbed
  • C: heat capacity of the calorimeter (37.60 kJ/K = 37.60 kJ/°C)
  • ΔT: temperature change (2.29 °C)

Q = 37.60 kJ/°C × 2.29 °C = 86.1 kJ

According to the law of conservation of energy, the heat released by the candy has the same magnitude as the heat absorbed by the calorimeter.

Step 2: Convert 86.1 kJ to Cal

We will use the conversion factor 1 Cal = 4.186 kJ.

86.1 kJ × 1 Cal/4.186 kJ = 20.6 Cal

Step 3: Calculate the number of Cal per gram of candy

20.6 Cal/6.70 g = 3.07 Cal/g

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Answer:

C_{alloy}=0.497\frac{J}{g\°C}

Explanation:

Hello there!

In this case, according to this calorimetry problem on equilibrium temperature, it is possible for us to infer that the heat released by the metal allow is absorbed by the water for us to write:

Q_{allow}=-(Q_{water}+Q_{Al})

Thus, by writing the aforementioned in terms of mass, specific heat and temperature, we have:

m_{alloy}C_{alloy}(T_{eq}-T_{alloy})=-(m_{water}C_{water}(T_{eq}-T_{water})+m_{Al}C_{Al}(T_{eq}-T_{Al})

Then, we solve for specific heat of the metallic alloy to obtain:

C_{alloy}=\frac{-(m_{water}C_{water}(T_{eq}-T_{water})+m_{Al}C_{Al}(T_{eq}-T_{Al})}{m_{alloy}(T_{eq}-T_{alloy})}

Thereby, we plug in the given data to obtain:

C_{alloy}=\frac{-(400g*4.184\frac{J}{g\°C} (30.5\°C-10.0\°C)+200g*0.900\frac{J}{g\°C}(30.5\°C-10.0\°C)}{150g(30.5\°C-540\°C)} \\\\C_{alloy}=0.497\frac{J}{g\°C}

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N is more electronative than H, so H will have a positive oxidation state and nitrogen will have a negative oxidation state.


You can also use the rule that states the hydrogen mostly has 1+ oxidation state,except when it is bonded to metals.


In conclusion the oxidation state of H in NH4 (1+) is 1+.


Now you must know that the sum of the oxidations states equals the charge of the ion, which in this case is 1+.


That implies that 4* (1+)  + x =   1+


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