A chemist dissolves 797. mg of pure barium hydroxide in enough water to make up 60. mL of solution. Calculate the pH of the solu
1 answer:
You might be interested in
Answer:The product formed on reaction with hydroxide ion as nucleophile is 2R-hexane-2-ol.
The product formed on reaction with water would be a 50:50 mixture of
2S-hexane-2-ol. and 2R-hexane-2-ol.
Explanation:
2S-iodohexane on reactiong with hydroxide ion would undergo SN² substitution reaction that is substitution bimolecular. Hydroxide ion has a negative charge and hence it is a quite good nucleophile .
The rate of a SN² reaction depends on both the substrate and nucleophile . Here the substrate is a secondary carbon center having Iodine as a leaving group.SN² reaction takes place here as hydroxide ion is a good nucleophile and it can attack the secondary carbon center from the back side leading to the formation of 2R-hexane-2-ol.
In a SN² reaction since the the nucleophile attacks from the back-side so the product formation takes place with the inversion of configuration.
When the same substrate S-2-iodohexane undergoes a substitution reaction with water as a nucleophile then the reaction occurs through (SN¹) substitution nucleophilic unimolecular mechanism .
The rate of a SN¹ reaction depends only on the nature of substrate and is independent of the nature of nucleophile.
The SN¹ reaction is a 2 step reaction , in the first step leaving group leaves leading to the formation of a carbocation and once the carbocation is formed then any weaker nucleophile or even solvent molecules can attack leading the formation of products.
In this case a secondary carbocation would be generated in the first step and then water will attack this carbocation to form the product in the second step.
The product formed on using water as a nucleophile would be a racemic mixture of R and S isomers of hexane -2-ol in 50:50 ratio. The two products formed would be 2R-hexane-2-ol and 2S-hexane-2-ol.
Kindly refer the attachment for reaction mechanism and structure of products.
Answer:
Answers are explained below
Explanation:
(a)
Oxidation number of iron :
FeO = +2
Fe2O3= +3
Fe3O4 = +2 and +3 since Fe3O4 is the mixture of FeO and Fe2O3.
(b) FeO + CO ----> Fe (s) + CO2
(c) In a pure iron metallic bond is exist between the particles of Fe. But in the form of ore metals forms ionic bond with the non-metals.
Hence the properties vary.
Yes carbon steel has greater strength than that of pure iron but retains the property of iron because no chemical reaction occurs between carbon and iron.
d)
Mixing of carbon in iron is a type of physical change since there is no chemical reactions occur between the carbon and iron. Carbon atoms diffuses in the place between the iron atoms.
(f) One of the property of non-metals are brittleness. It is non ductile .
So when the percentage of carbon increases its atoms also occupying more and more free places.
And increasing the brittleness. So the iron becomes less ductile.
e)
