Question

Compute the theoretical density of ZnS given that the Zn-S distance and bond angle are 0.234 nm and 109.5o, respectively. The atomic weights of zinc and sulfur are 65.41 g/mol and 32.06 g/mol.

Answer 1

Answer: the theoretical density is 4.1109 g/cm³

Explanation:  

first the image of one set of ZnS bonding in the crystal structure, we calculate the value of angle θ

θ + ∅ + 90° = 180°

θ = 90° - ∅

θ = 90° - ( 109.5° / 2 )

θ = 35.25°

next we calculate the value of x from the geometry

given that;  distance angle d = 0.234

x = dsinθ

= 0.234 × sin35.25°)

= 0.135 nm = 0.135 × 10⁻⁷ cm

next we calculate the length of the unit cell

a = 4x

a = 4(0.135)

a = 0.54 nm = 0.54 × 10⁻⁷ cm

next we calculate number of formula units

n' = (no of corner atoms in unit ell × contribution of each corner atom in unit cell) + ( no of face center atom in a unit cell × contribution of each face center atom in a unit cell)

n' = 8 × 1/8) + ( 6 × 1/2)

= 1 + 3

= 4

next we calculate the theoretical density using  this equation

P = [n'∑(Ac + AA)] / [Vc.NA]

= [n'∑(Ac + AA)] / [(a)³NA]

where the ∑Ac is sum of atomic weights of all cations in the formula unit( 65.41 g/mol)

∑AA is the sum of weights of all anions in the formula unit( 32.06 g/mol)

Na is the Avogadro’s number( 6.023 × 10²³ units/mole)

so we substitute

P = [4( 65.41 + 32.06)] / [ ( 0.54 × 10⁻⁷ )³ × (6.023 × 10²³)]

= 389.88 / 94.84

= 4.1109 g/cm³

therefore the theoretical density is 4.1109 g/cm³