Answer: the reliability will be worse
Explanation:
Suppose we used 0.5 M NaOH to titrate our vinegar sample instead of 0.1 M.
Now by using 0.5M instead of 0.1M we are increasing the concentration of NaOH,
We know that the moles used = Volume x concnetration.
so for the same no of moles, if the concentration increases, the volume decreases.
Hence it will consume less NaOH.
now Since the volume decreases, the titration volume of less number will increase the % error.
Therefore the reliability will be worse.
Sulfur is a group six element in period 3 with atomic number 16 and an electronic configuration of 2:8:6. Therefore, to attain a stable configuration it requires to gain two electrons forming an ion with a charge of -2. The negative charge is due to the gaining of electrons.
Answer:
The ratio of f at the higher temperature to f at the lower temperature is 5.356
Explanation:
Given;
activation energy, Ea = 185 kJ/mol = 185,000 J/mol
final temperature, T₂ = 525 K
initial temperature, T₁ = 505 k
Apply Arrhenius equation;
![Log(\frac{f_2}{f_1} ) = \frac{E_a}{2.303 \times R} [\frac{1}{T_1} -\frac{1}{T_2} ]](https://tex.z-dn.net/?f=Log%28%5Cfrac%7Bf_2%7D%7Bf_1%7D%20%29%20%3D%20%5Cfrac%7BE_a%7D%7B2.303%20%5Ctimes%20R%7D%20%5B%5Cfrac%7B1%7D%7BT_1%7D%20-%5Cfrac%7B1%7D%7BT_2%7D%20%5D)
Where;
is the ratio of f at the higher temperature to f at the lower temperature
R is gas constant = 8.314 J/mole.K
![Log(\frac{f_2}{f_1} ) = \frac{E_a}{2.303 \times R} [\frac{1}{T_1} -\frac{1}{T_2} ]\\\\Log(\frac{f_2}{f_1} ) = \frac{185,000}{2.303 \times 8.314} [\frac{1}{505} -\frac{1}{525} ]\\\\Log(\frac{f_2}{f_1} ) = 0.7289\\\\\frac{f_2}{f_1} = 10^{0.7289}\\\\\frac{f_2}{f_1} = 5.356](https://tex.z-dn.net/?f=Log%28%5Cfrac%7Bf_2%7D%7Bf_1%7D%20%29%20%3D%20%5Cfrac%7BE_a%7D%7B2.303%20%5Ctimes%20R%7D%20%5B%5Cfrac%7B1%7D%7BT_1%7D%20-%5Cfrac%7B1%7D%7BT_2%7D%20%5D%5C%5C%5C%5CLog%28%5Cfrac%7Bf_2%7D%7Bf_1%7D%20%29%20%3D%20%5Cfrac%7B185%2C000%7D%7B2.303%20%5Ctimes%208.314%7D%20%5B%5Cfrac%7B1%7D%7B505%7D%20-%5Cfrac%7B1%7D%7B525%7D%20%5D%5C%5C%5C%5CLog%28%5Cfrac%7Bf_2%7D%7Bf_1%7D%20%29%20%3D%200.7289%5C%5C%5C%5C%5Cfrac%7Bf_2%7D%7Bf_1%7D%20%20%3D%2010%5E%7B0.7289%7D%5C%5C%5C%5C%5Cfrac%7Bf_2%7D%7Bf_1%7D%20%20%3D%205.356)
Therefore, the ratio of f at the higher temperature to f at the lower temperature is 5.356
