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Dominik [7]
3 years ago
8

1-butanol yields 1-bromobutane in the presence of concentrated sulfuric acid and an excess of sodium bromide. CH3CH2CH2CH2OH (l)

→ CH3 CH2CH2CH2Br (l) If 15.89 mL of 1-butanol produced 12.23 g of 1-bromobutane, the percentage yield of the product equals: (Assume the density of 1-butanol is 0.81 g/mL, the molar mass of 1-butanol is 74 g/mol, and the molar mass of 1-bromobutane is 137 g/mol.)
Chemistry
1 answer:
Goshia [24]3 years ago
4 0

Answer:

51.34 %

Explanation:

You first need to calculate the theoretical yield of Bromobutane taking into account the amount of initial Butanol doing some stoichiometric calculations:

15.89 mL Butanol*\frac{0.81 g Butanol}{1 mL}*\frac{1 mol Butanol}{74 g} *\frac{1 mol Bromobutane  Produced}{1 mol Butanol Consumed} *\frac{137g }{1 mol Bromobutane} =23.83 g Bromobutane Produced

Then you calculate the yield giving the real amount you produced:

Yield=\frac{12.23 g}{23.82 g} *100=51.34%

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<u>Answer:</u> The concentration of salt (sodium sulfate), sulfuric acid and NaOH in the solution is 0.0418 M, 0.0999 M and 0 M respectively.

<u>Explanation:</u>

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0.195M=\frac{\text{Moles of NaOH}}{0.015L}\\\\\text{Moles of NaOH}=(0.195mol/L\times 0.015L)=2.925\times 10^{-3}mol

<u>For sulfuric acid:</u>

Initial molarity of sulfuric acid solution = 0.248 M

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0.248M=\frac{\text{Moles of }H_2SO_4}{0.020L}\\\\\text{Moles of }H_2SO_4=(0.248mol/L\times 0.020L)=4.96\times 10^{-3}mol

The chemical equation for the reaction of NaOH and sulfuric acid follows:

2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O

By Stoichiometry of the reaction:

2 moles of NaOH reacts with 1 mole of sulfuric acid

So, 2.925\times 10^{-3} moles of KOH will react with = \frac{1}{2}\times 2.925\times 10^{-3}=1.462\times 10^{-3}mol of sulfuric acid

As, given amount of sulfuric acid is more than the required amount. So, it is considered as an excess reagent.

Thus, NaOH is considered as a limiting reagent because it limits the formation of product.

Excess moles of sulfuric acid = (4.96-1.462)\times 10^{-3}=3.498\times 10^{-3}mol

By Stoichiometry of the reaction:

2 moles of KOH produces 1 mole of sodium sulfate

So, 2.925\times 10^{-3} moles of KOH will produce = \frac{1}{2}\times 2.925\times 10^{-3}=1.462\times 10^{-3}mol of sodium sulfate

  • <u>For sodium sulfate:</u>

Moles of sodium sulfate = 1.462\times 10^{-3}moles

Volume of solution = [15.0 + 20.0] = 35.0 mL = 0.035 L

Putting values in equation 1, we get:

\text{Molarity of sodium sulfate}=\frac{1.462\times 10^{-3}}{0.035}=0.0418M

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Moles of excess sulfuric acid = 3.498\times 10^{-3}mol

Volume of solution = [15.0 + 20.0] = 35.0 mL = 0.035 L

Putting values in equation 1, we get:

\text{Molarity of sulfuric acid}=\frac{3.498\times 10^{-3}}{0.035}=0.0999M

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Moles of NaOH remained = 0 moles

Volume of solution = [15.0 + 20.0] = 35.0 mL = 0.035 L

Putting values in equation 1, we get:

\text{Molarity of NaOH}=\frac{0}{0.050}=0M

Hence, the concentration of salt (sodium sulfate), sulfuric acid and NaOH in the solution is 0.0418 M, 0.0999 M and 0 M respectively.

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