1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
Agata [3.3K]
2 years ago
5

The formation of tert-butanol is described by the following chemical equation: Suppose a two-step mechanism is proposed for this

reaction, beginning with this elementary reaction: Suppose also that the second step of the mechanism should be bimolecular. Suggest a reasonable second step. That is, write the balanced chemical equation of a bimolecular elementary reaction that would complete the proposed mechanism.
Chemistry
1 answer:
const2013 [10]2 years ago
5 0

Answer:

(CH3)3C^+ + OH^-  --------> (CH3)3COH

Explanation:

This reaction has to do with SN1 reaction of alkyl halides. Here tert-butanol is formed from tert-butyl bromide.

The first step in the reaction is the formation of a carbocation. This is a unimolecular reaction. The rate of reaction depends on the concentration of the alkyl halide. This is a slow step and thus the rate determining step in the mechanism.

(CH3)3CBr -------> (CH3)3C^+ + Br^-

The second step is a fast step and it completes the reaction mechanism. It is a bimolecular reaction as follows;

(CH3)3C^+ + OH^-  --------> (CH3)3COH

You might be interested in
Learn how changes in binding free energy affect binding and the ratio of unbound and bound molecules.
Delvig [45]

C)[D]/[ED] = 5.20

D)[D]/[ED] = 5.20

E)[D']_T = 1.495* 10 ^-7 M

F)[D'] / [ED']  = 0.0579

Explanation:

E = 250 nM =2.5* 10 ^-7 mol/L , T=298.15 K

Dissociation constant of K_D = 1.3 μM (1.3 *10 ^-6 M)

E + D ⇄ ED → K_a = [ED] / [D][E]   (association constant)

ED ⇄ E + D → K_D = [E][D] / [ED]  (dissociation constant)

C)

[E] =2.5*10^-7 mol/L

K_D = 1.3* 10^-6 M

K_D = [E][D] / [ED] → [D]/[ED] = K_D / [E]

= [D]/[ED] = 1.3* 10 ^-6 / 2.5 *10^-7

= 13/25 * 10

=130/25 = 5.20

[D]/[ED] = 5.20

D)

ΔG =RTln Kd

ΔG_2 for E and D = 1.987 * 298.15 * ln 1.3*10^-6

ΔG_2 592.454 * [ln 1.3 +ln 10^-6]

ΔG_1 = 592.424 [0.2623 - 13.8155]

ΔG_2 = -592.424 * 13.553

ΔG_1 = -8184.633 cal/ mol

ΔG_1 = -8184.633  * 4.18 J/mol = -34244.508 J?mol

ΔG_1 = -34.245 KL/mol

so, ΔG_2 = ΔG_1 - 10.5 KJ/mol

ΔG_2 = -34.245 - 10.5

ΔG_2 = -44.745KJ / mol

ΔG_2 =RT ln K_D

-44.745 *10^3

=8.314 *298.15 lnK_D

lnK_D' = - 44745 / 2478.81 g

ln K_D' = -18.051

K_D' = -18.051

K_D' = e^-18.051

[D]/[ED] = 5.20

E)

[E] = 2.5* 10 ^-7 mol/ L = a

K_D' = [E][D] / [ED']                                  E +D' → ED'

K_D' = a/2(x-(a/2) / (a/2)

KD' = x - a/2

=2.447 *10^-8 = (2.5/2) * 10^-7

x=2.447 * 10^-8 + 1.25 * 10^-7

x = 2.447 *10^-8 + 1.25 * 10 ^-7

x= 10^-7 [1.25 + 0.2447]

x = 1.4947 * 10^-7

[D']_T = 1.495* 10 ^-7 M

F)

K_D' = [E][D'] / [ED']

[D'] / [ED'] = KD' / [E]

[D'] / [ED'] = 1.447 *10^-8 / 2.5* 10^-7

[D'] / [ED'] = 0.5788 * 10^-1

[D'] / [ED']  = 0.0579

5 0
3 years ago
The fifth element in group 7 in astatine would you expect it to be gas, liquid, or solid? why?
Ymorist [56]

Answer:

solid

Explanation:

Melting and boiling points of Group 7 elements State at room temperature Room temperature is usually taken as being 25°C. At this temperature, fluorine and chlorine are gases, bromine is a liquid, and iodine and astatine are solids. There is therefore a trend in state from gas to liquid to solid as you go down the group.

6 0
1 year ago
The molecular clock theory uses genetic traits to estimate how long ago various groups of organisms diverged evolutionary from o
Nataliya [291]
<span>Many scientific investigations have provided evidence to support this as the best explanation of the data</span>
8 0
2 years ago
Read 2 more answers
Which of the following methods can be used to remove water from a mixture of sand and water? A. Centrifuge B. Filtration C. Floa
wlad13 [49]
The correct answer is b. filtration
3 0
3 years ago
Read 2 more answers
How many ions in 6.41 moles of K2O? Please show work.
Oksana_A [137]
1. Convert the number of moles to number of particles (divide 6.41 by 6.022 x 10^23)

2. K2O dissociates into three ions (2 potassium ions and 1 oxide ion), so multiply the result from step 1 by 3 to get your answer
4 0
2 years ago
Other questions:
  • Which of the following shows both the correct formula and correct name of an acid?
    13·2 answers
  • How do you write the formula for potassium hydroxide
    7·2 answers
  • Consider a 125 mL buffer solution at 25°C that contains 0.500 mol of hypochlorous acid (HOCl) and 0.500 mol of sodium hypochlori
    13·1 answer
  • What is needed for work to be done?
    15·2 answers
  • Is this right if not pls lmk what the correct answer is:)
    6·1 answer
  • the figure shows particles of a substance in a closed container. Which state of matter is shown in the figure?
    7·1 answer
  • What is the [SO32-) in the 0.080 M H2SO3 .080 M Solution?
    13·1 answer
  • How much iron(III) oxide is produced? Answer in units of g.
    8·1 answer
  • Why doesn’t the addition of an acid-base indicator affect the pH of the test solution?
    12·1 answer
  • Lake Baikal in Siberia is the largest freshwater body on Earth by volume, at 5666 mi³
    11·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!