The overall rate law in terms of the initial rate of the reaction is:
= ![k_{overall} [H_{2} SO_{4} ]^{2} [C_{6}H_{6}]](https://tex.z-dn.net/?f=k_%7Boverall%7D%20%5BH_%7B2%7D%20SO_%7B4%7D%20%5D%5E%7B2%7D%20%5BC_%7B6%7DH_%7B6%7D%5D)
The Sulfonation of benzene has the following mechanism:
(1)
⇌ 
[fast]
(2)
→ 
[slow]
(3) 
→ 
[fast]
(4)
→ 
[fast]
<h3>Calculation of rate law:</h3>
Given that the reaction's slowest step is the rate-dependent step, the following is the definition of rate law:
Rate =
However, the issue is that because
is an intermediate, it cannot be accounted for in the general rate legislation.
The following rate rule governs the synthesis of
:
Rate = ![k_{1}[H_{2} SO_{4} ]^{2}](https://tex.z-dn.net/?f=k_%7B1%7D%5BH_%7B2%7D%20SO_%7B4%7D%20%20%5D%5E%7B2%7D)
Consequently, if we replace equation 1 with equation 2,
Rate is determined to be = ![k_{overall} [H_{2} SO_{4} ]^{2} [C_{6}H_{6}]](https://tex.z-dn.net/?f=k_%7Boverall%7D%20%5BH_%7B2%7D%20SO_%7B4%7D%20%5D%5E%7B2%7D%20%5BC_%7B6%7DH_%7B6%7D%5D)
Hence, the overall rate law in terms of the initial rate of the reaction is:
= ![k_{overall} [H_{2} SO_{4} ]^{2} [C_{6}H_{6}]](https://tex.z-dn.net/?f=k_%7Boverall%7D%20%5BH_%7B2%7D%20SO_%7B4%7D%20%5D%5E%7B2%7D%20%5BC_%7B6%7DH_%7B6%7D%5D)
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Answer: hello some part of your question is missing below is the missing part
In an experiment to determine the % of ascorbic acid in Vitamin C Tablets by Titration with Potassium Bromate,
answer:
Oxidation half reaction of Vitamin C
Explanation:
The solution will turn cloudy dark purple even after reaching endpoint when allowed to settle with time. because of the Oxidation half reaction of Vitamin C. also during the Titration process few drops of starch solution will be added to help determine the endpoint of the experiment .
Answer : The correct option is C.
Explanation :
Enthalpy of reaction : It is defined as the changes in heat energy takes place when reactants go to products. It is denotes as
.
= Energy of product - Energy of reactant
is positive when heat is absorbed and the reaction is endothermic.
is negative when heat is released and the reaction is exothermic.
In the given potential energy diagram, the energy of product at higher level and energy of reactant at lower level. The
for this reaction will be positive.
So, the enthalpy of reaction is defined as the difference of the energy of the reactants and the energy of the products.