<span>[Cu(NH3)4]2+ forms a blue solution. When concentrated HCl is added to this solution, what color will the solution change to yellow.
Reason:
When conc. HCl is added to the solution containing </span>[Cu(NH3)4]2+, Cl- ions will replace NH3 and form [Cu(Cl)4]2- complex. This can be understood for the following reaction:
[Cu(NH3)4]2+ + Cl- ↔ [Cu(Cl)4]2- + NH3
The Cl- ion is a weak field ligand, while NH3 is a strong field ligand. Hence, Cl- will in less splitting of d-orbitals, as compared to NH3. Due to this, photons of different energies will be absorbed by these complexes, and hence they display different colours.
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Answer:
hydrochloride acidic maby
Explanation:
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