Answer:
Less
Explanation:
Since [Cu(NH3)4]2+ and [Cu(H2O)6]2+ are Octahedral Complexes the transitions between d-levels explain the majority of the absorbances seen in those chemical compounds. The difference in energy between d-levels is known as ΔOh (ligand-field splitting parameter) and it depends on several factors:
- The nature of the ligand: A spectrochemical series is a list of ligands ordered on ligand strength. With a higher strength the ΔOh will be higher and thus it requires a higher energy light to make the transition.
- The oxidation state of the metal: Higher oxidation states will strength the ΔOh because of the higher electrostatic attraction between the metal and the ligand
A partial spectrochemical series listing of ligands from small Δ to large Δ:
I− < Br− < S2− < Cl− < N3− < F−< NCO− < OH− < C2O42− < H2O < CH3CN < NH3 < NO2− < PPh3 < CN− < CO
Then NH3 makes the ΔOh higher and it requires a higher energy light to make the transition, which means a shorter wavelength.
Ms ( mass of solute): 33,6g
mss (mass of solution): 33,6+192g = 225,6g
__________________
C = ms/mss × 100%
C = 33.6/225.6 × 100%
C = 14,89% ≈ 14,9%
:•)
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