Answer:
Explanation:
All three lighter boron trihalides, BX3 (X = F, Cl, Br), form stable adducts with common Lewis bases. Their relative Lewis acidities can be evaluated in terms of the relative exothermicities of the adduct-forming reaction. Such measurements have revealed the following sequence for the Lewis acidity: BF3 < BCl3 < BBr3 (in other words, BBr3 is the strongest Lewis acid).
This trend is commonly attributed to the degree of π-bonding in the planar boron trihalide that would be lost upon pyramidalization (the conversion of the trigonal planar geometry to a tetrahedral one) of the BX3 molecule, which follows this trend: BF3 > BCl3 > BBr3 (that is, BBr3 is the most easily pyramidalized). The criteria for evaluating the relative strength of π-bonding are not clear, however. One suggestion is that the F atom is small compared to the larger Cl and Br atoms, and the lone pair electron in the 2pzorbital of F is readily and easily donated, and overlaps with the empty 2pz orbital of boron. As a result, the [latex]\pi[/latex] donation of F is greater than that of Cl or Br. In an alternative explanation, the low Lewis acidity for BF3 is attributed to the relative weakness of the bond in the adducts F3B-L.
Answer:
Final volume 30.513 L.
Explanation:
According to general gas equation:
P₁V₁/T₁ = P₂V₂/T₂
Given data:
Initial volume = 17 L
Initial pressure = 2.3 atm
Initial temperature = 299 K
Final temperature = 350 K
Final volume = ?
Final pressure = 1.5 atm
Solution:
P₁V₁/T₁ = P₂V₂/T₂
V₂ = P₁V₁ T₂/ T₁ P₂
V₂ = 2.3 atm × 17 L × 350 K / 299 K × 1.5 atm
V₂ = 13685 atm .L. K / 448.5 K . atm
V₂ = 30.513 L
Answer:
HOAc is stronger acid than HClO
ClO⁻ is stronger conjugate base than OAc⁻
Kb(OAc⁻) = 5.5 x 10⁻¹⁰
Kb(ClO⁻) = 3.3 x 10⁻⁷
Explanation:
Assume 0.10M HOAc => H⁺ + OAc⁻ with Ka = 1.8 x 10⁻⁵
=> [H⁺] = √Ka·[Acid] =√(1.8 x 10⁻⁵)(0.10) M = 1.3 x 10⁻³M H⁺
Assume 0.10M HClO => H⁺ + ClO⁻ with Ka = 3 x 10⁻⁸
=> [H⁺] = √(3 x 10⁻⁸)(0.10)M = 5.47 x 10⁻⁵M H⁺
HOAc delivers more H⁺ than HClO and is more acidic.
Kb = Kw/Ka, Kw = 1 x 10⁻¹⁴
Kb(OAc⁻) = 5.5 x 10⁻¹⁰
Kb(ClO⁻) = 3.3 x 10⁻⁷
There are a lot of ways to increase the solubility of the solute. <span>Increasing the temperature, mixing time and surface area of a solvent increases the solubility of the solute</span>
