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spayn [35]
2 years ago
14

If you have 100 ml of a 0.10 m tris buffer (pka 8.3) at ph 8.3 and you add 3.0 ml of 1.0 m hcl, what will be the new ph?

Chemistry
1 answer:
sukhopar [10]2 years ago
8 0

The new pH is 7.69.

According to Hendersen Hasselbach equation;

The Henderson Hasselbalch equation is an approximate equation that shows the relationship between the pH or pOH of a solution and the pKa or pKb and the ratio of the concentrations of the dissociated chemical species. To calculate the pH of the buffer solution made by mixing salt and weak acid/base. It is used to calculate the pKa value. Prepare buffer solution of needed pH.

                       pH = pKa + log10 ([A–]/[HA])

Here, 100 mL  of  0.10 m TRIS buffer pH 8.3

                 pka = 8.3

         0.005 mol of TRIS.

∴  8.3 = 8.3 + log \frac{[0.005]}{[0.005]}

<em>    </em>inverse log 0 = \frac{[B]}{[A]}

   \frac{[B]}{[A]} = 1

Given; 3.0 ml of 1.0 m hcl.

           pka = 8.3

           0.003 mol of HCL.

pH = 8.3 + log \frac{[0.005-0.003]}{[0.005+0.003]}\\pH = 8.3 + log \frac{[0.002]}{[0.008]}\\\\pH = 8.3 + log {0.25}\\\\pH = 8.3 + (-0.62)\\pH = 7.69

Therefore, the new pH is 7.69.

Learn more about pH here:

brainly.com/question/24595796

#SPJ1

 

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Naturally occurring silicon has an atomic mass of 28.086 and consists of three isotopes. The major isotope is 28Si, natural abun
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Answer:

29Si has a natural abundance of 4.68%.

30Si has a relative atomic mass of 29.99288 and a natural abundance of 3.09%.

Explanation:

The atomic mass of silicon is given by:

Si=Si²⁸×A₁+Si²⁹×A₂+Si³⁰×A₃

Where:

Si: atomic mass of silicon (28.086)

Si²⁸: relative atomic mass of 28Si (27.97693)

A₁: natural abundance of 28Si (92.23%)

Si²⁹: relative atomic mass of 29Si (28.97649)

A₂: natural abundance of 29Si

Si³⁰: relative atomic mass of 30Si

A₃: natural abundance of 30Si

We also know that 30Si natural abundance is in the ratio of 0.6592 to that of 29Si.

We have to set up a system of three equations in three unknowns:

Si=Si²⁸×A₁+Si²⁹×A₂+Si³⁰×A₃

A₃=0.6592×A₂

A₁+A₂+A₃=1

First, we find substitute the value of A₃ in the third equation and solv teh value of A₂:

A₁+A₂+0.6592×A₂=1

A₁+1.6592×A₂=1

1.6592×A₂=1-A₁

A₂=\frac{1-A₁}{1.6592}=\frac{1-0.9223}{1.6592}=0.0468

Then, we find the value of A₃:

A₃=0.6592×A₂

A₃=0.6592×0.0468=0.0309

Finally, we find the value of Si³⁰ in the first equation:

Si=Si²⁸×A₁+Si²⁹×A₂+Si³⁰×A₃

28.086=27.97693×0.9223+28.97649×0.0468+Si³⁰×0.0309

28.086=27.15922+Si³⁰×0.0309

28.086-27.15922=Si³⁰×0.0309

\frac{0.92678}{0.0309}=Si³⁰

Si³⁰=29.99288

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