If you have 100 ml of a 0.10 m tris buffer (pka 8.3) at ph 8.3 and you add 3.0 ml of 1.0 m hcl, what will be the new ph?
1 answer:
The new pH is 7.69.
According to Hendersen Hasselbach equation;
The Henderson Hasselbalch equation is an approximate equation that shows the relationship between the pH or pOH of a solution and the pKa or pKb and the ratio of the concentrations of the dissociated chemical species. To calculate the pH of the buffer solution made by mixing salt and weak acid/base. It is used to calculate the pKa value. Prepare buffer solution of needed pH.
pH = pKa + log10 ([A–]/[HA])
Here, 100 mL of 0.10 m TRIS buffer pH 8.3
pka = 8.3
0.005 mol of TRIS.
∴
<em> </em>inverse log 0 =
Given; 3.0 ml of 1.0 m hcl.
pka = 8.3
0.003 mol of HCL.
Therefore, the new pH is 7.69.
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Answer: The volume of required is 25.0 ml
Explanation:
According to the neutralization law,
where,
= basicity
= 1
= molarity of
solution = 2.00 M
= volume of
solution = 50.0 ml
= acidity of
= 1
= molarity of
solution = 4.00 M
= volume of
solution = ?
Putting in the values we get:
Therefore, volume of required is 25.0 ml