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oksian1 [2.3K]
3 years ago
10

Use bond energies to determine δhrxn for the reaction between ethanol and hydrogen chloride. ch3ch2oh(g)+hcl(g)âch3ch2cl(g)+h2o

(g)

Chemistry
1 answer:
Alex3 years ago
6 0
For this reaction to proceed, the following bond breaking should occur: 
*one C-O bond* one H-Cl bond
After, the following bond formations should occur:*one C-Cl bond*one O-H bond
Now, add the bond energies for the respective bond energies which can be found in the attached picture. For bond formations, energy is negative. For bond breaking, energy is positive.
ΔHrxn = (1)(358) + (1)(431) + 1(-328) + 1(-463) =<em> -2 kJ</em>

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(1) The solubility of Salt AB2(S) IS 5mol/dm^3.
Svetlanka [38]

Answer:

a. Ksp = 4s³

b. 5.53 × 10⁴ mol³/dm⁹

Explanation:

a. Obtain an expression for the solubility product of AB2(S),in terms of s.

AB₂ dissociates to give

AB₂ ⇄ A²⁺ + 2B⁻

Since 1 mole of AB₂ gives 1 mole of A and 2 moles of B, we have the mole ratio as

AB₂ ⇄ A²⁺ + 2B⁻

1 : 1 : 2

Since the solubility of AB₂ is s, then the solubility of A is s and that of B is 2s

So, we have

AB₂ ⇄ A²⁺ + 2B⁻

[s]        [s]    [2s]

So, the solubility product Ksp = [A²⁺][B⁻]²

= (s)(2s)²

= s(4s²)

= 4s³

b. Calculate the Ksp of AB₂, given that solubility is 2.4 × 10³ mol/dm³

Given that the solubility of AB is 2.4 × 10³ mol/dm³ and the solubility product Ksp = [A²⁺][B⁻]² = 4s³ where s = solubility of AB = 2.4 × 10³ mol/dm³

Substituting the value of s into the equation, we have

Ksp = 4s³

= 4(2.4 × 10³ mol/dm³)³

= 4(13.824 × 10³ mol³/dm⁹)

= 55.296 × 10³ mol³/dm⁹

= 5.5296 × 10⁴ mol³/dm⁹

≅ 5.53 × 10⁴ mol³/dm⁹

Ksp = 5.53 × 10⁴ mol³/dm⁹

6 0
2 years ago
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